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Hybrid complexes incorporating synthetic Mn-porphyrins into an artificial four-helix bundle domain of bacterial reaction centers created a system to investigate new electron transfer pathways. The reactions were initiated by illumination of the bacterial reaction centers, whose primary photochemistry involves electron transfer from the bacteriochlorophyll dimer through a series of electron acceptors to the quinone electron acceptors. Porphyrins with diphenyl, dimesityl, or fluorinated substituents were synthesized containing either Mn or Zn. Electrochemical measurements revealed potentials for Mn(III)/Mn(II) transitions that are ~ 0.4 V higher for the fluorinated Mn-porphyrins than the diphenyl and dimesityl Mn-porphyrins. The synthetic porphyrins were introduced into the proteins by binding to a four-helix bundle domain that was genetically fused to the reaction center. Light excitation of the bacteriochlorophyll dimer of the reaction center resulted in new derivative signals, in the 400 to 450 nm region of light-minus-dark spectra, that are consistent with oxidation of the fluorinated Mn(II) porphyrins and reduction of the diphenyl and dimesityl Mn(III) porphyrins. These features recovered in the dark and were not observed in the Zn(II) porphyrins. The amplitudes of the signals were dependent upon the oxidation/reduction midpoint potentials of the bacteriochlorophyll dimer. These results are interpreted as photo-induced charge-separation processes resulting in redox changes of the Mn-porphyrins, demonstrating the utility of the hybrid artificial reaction center system to establish design guidelines for novel electron transfer reactions. 

Abstract We present ultraviolet to infrared observations of the extraordinary Type IIn supernova 2023zkd (SN 2023zkd). Photometrically, it exhibits persistent and luminous precursor emission spanning ∼4 yr preceding discovery (M_r ≈ −15 mag, 1500 days in the observer frame), followed by a secondary stage of gradual brightening in its final year. Post-discovery, it exhibits two photometric peaks of comparable brightness (M_r ≲ −18.7 mag andM_r ≈ −18.4 mag, respectively) separated by 240 days. Spectroscopically, SN 2023zkd exhibits highly asymmetric and multicomponent Balmer and HeIprofiles that we attribute to ejecta interaction with fast-moving (1000–2000 km s⁻¹) He-rich polar material and slow-moving (∼400 km s⁻¹) equatorially distributed H-rich material. HeIIfeatures also appear during the second light curve peak and evolve rapidly. Shock-driven models fit to the multiband photometry suggest that the event is powered by interaction with ∼5–6M_⊙of CSM, with 2–3M_⊙associated with each light curve peak, expelled during mass-loss episodes ∼3–4 yr and ∼1–2 yr prior to explosion. The observed precursor emission, combined with the extreme mass-loss rates required to power each light curve peak, favors either super-Eddington accretion onto a black hole or multiple long-lived eruptions from a massive star to luminosities that have not been previously observed. We consider multiple progenitor scenarios for SN 2023zkd, and find that the brightening optical precursor and inferred explosion properties are most consistent with a massive (M_ZAMS≥ 30M_⊙) and partially stripped He star undergoing an instability-induced merger with a black hole companion. 

SN 2020zbf is a hydrogen-poor superluminous supernova (SLSN) atz = 0.1947 that shows conspicuous C IIfeatures at early times, in contrast to the majority of H-poor SLSNe. Its peak magnitude isM_g = −21.2 mag and its rise time (≲26.4 days from first light) places SN 2020zbf among the fastest rising type I SLSNe. We used spectra taken from ultraviolet (UV) to near-infrared wavelengths to identify spectral features. We paid particular attention to the C IIlines as they present distinctive characteristics when compared to other events. We also analyzed UV and optical photometric data and modeled the light curves considering three different powering mechanisms: radioactive decay of⁵⁶Ni, magnetar spin-down, and circumstellar medium (CSM) interaction. The spectra of SN 2020zbf match the model spectra of a C-rich low-mass magnetar-powered supernova model well. This is consistent with our light curve modeling, which supports a magnetar-powered event with an ejecta massM_ej = 1.5 M_⊙. However, we cannot discard the CSM-interaction model as it may also reproduce the observed features. The interaction with H-poor, carbon-oxygen CSM near peak light could explain the presence of C IIemission lines. A short plateau in the light curve around 35–45 days after peak, in combination with the presence of an emission line at 6580 Å, can also be interpreted as being due to a late interaction with an extended H-rich CSM. Both the magnetar and CSM-interaction models of SN 2020zbf indicate that the progenitor mass at the time of explosion is between 2 and 5M_⊙. Modeling the spectral energy distribution of the host galaxy reveals a host mass of 10^8.7M_⊙, a star formation rate of 0.24_−0.12^+0.41M_⊙yr⁻¹, and a metallicity of ∼0.4Z_⊙. 

Abstract We present photometric and spectroscopic data for the nearby Type I supernova (SN Ia) 2019eix (originally classified as an SN Ic), from the day of its discovery up to 100 days after maximum brightness. Before maximum light, SN 2019eix resembles a typical SN Ic, albeit lacking the usual Oifeature. Its light curve is similar to the typical SN Ic with decline rates (ΔM_15,V= 0.84) and absolute magnitudeM_V= −18.35. However, after maximum light, this SN has unusual spectroscopic features, a large degree of line blending, significant line blanketing in the blue (λ< 5000 Å), and strong Caiiabsorption features during and after peak brightness. These unusual spectral features are similar to models of subluminous thermonuclear explosions, specifically double-detonation models of SNe Ia. Photometrically, SN 2019eix appears to be somewhat brighter with slower decline rates than other double-detonation candidates. We modeled the spectra using the radiative-transfer codeTARDISusing SN 1994I (an SN Ic) as a base model to see whether we could reproduce the unusual features of SN 2019eix and found them to be consistent with the exception of the Oifeature. We also compared SN 2019eix with double-detonation models and found them to best match the observations of SN 2019eix, but failed to reproduce its full photometric and spectroscopic evolution. 

ABSTRACT Near-infrared (NIR) observations of normal Type Ia supernovae (SNe Ia) obtained between 150 and 500 d past maximum light reveal the existence of an extended plateau. Here, we present observations of the underluminous, 1991bg-like SN 2021qvv. Early, ground-based optical and NIR observations show that SN 2021qvv is similar to SN 2006mr, making it one of the dimmest, fastest evolving 1991bg-like SNe to date. Late-time (170–250 d) Hubble Space Telescope observations of SN 2021qvv reveal no sign of a plateau. An extrapolation of these observations backwards to earlier-phase NIR observations of SN 2006mr suggests the complete absence of an NIR plateau, at least out to 250 d. This absence may be due to a higher ionization state of the ejecta, as predicted by certain sub-Chandrasekhar-mass detonation models, or to the lower temperatures of the ejecta of 1991bg-like SNe, relative to normal SNe Ia, which might preclude their becoming fluorescent and shifting ultraviolet light into the NIR. This suggestion can be tested by acquiring NIR imaging of a sample of 1991bg-like SNe that covers the entire range from slowly evolving to fast-evolving events (0.2 ≲ sBV ≲ 0.6). A detection of the NIR plateau in slower evolving, hotter 1991bg-like SNe would provide further evidence that these SNe exist along a continuum with normal SNe Ia. Theoretical progenitor and explosion scenarios would then have to match the observed properties of both SN Ia subtypes. 

We present photometric and spectroscopic observations of SN 2020xga and SN 2022xgc, two hydrogen-poor superluminous supernovae (SLSNe-I) atz = 0.4296 andz = 0.3103, respectively, which show an additional set of broad Mg IIabsorption lines, blueshifted by a few thousands kilometer second⁻¹with respect to the host galaxy absorption system. Previous work interpreted this as due to resonance line scattering of the SLSN continuum by rapidly expanding circumstellar material (CSM) expelled shortly before the explosion. The peak rest-frameg-band magnitude of SN 2020xga is −22.30 ± 0.04 mag and of SN 2022xgc is −21.97 ± 0.05 mag, placing them among the brightest SLSNe-I. We used high-quality spectra from ultraviolet to near-infrared wavelengths to model the Mg IIline profiles and infer the properties of the CSM shells. We find that the CSM shell of SN 2020xga resides at ∼1.3 × 10¹⁶cm, moving with a maximum velocity of 4275 km s⁻¹, and the shell of SN 2022xgc is located at ∼0.8 × 10¹⁶cm, reaching up to 4400 km s⁻¹. These shells were expelled ∼11 and ∼5 months before the explosions of SN 2020xga and SN 2022xgc, respectively, possibly as a result of luminous-blue-variable-like eruptions or pulsational pair instability (PPI) mass loss. We also analyzed optical photometric data and modeled the light curves, considering powering from the magnetar spin-down mechanism. The results support very energetic magnetars, approaching the mass-shedding limit, powering these SNe with ejecta masses of ∼7 − 9 M_⊙. The ejecta masses inferred from the magnetar modeling are not consistent with the PPI scenario pointing toward stars > 50 M_⊙He-core; hence, alternative scenarios such as fallback accretion and CSM interaction are discussed. Modeling the spectral energy distribution of the host galaxy of SN 2020xga reveals a host mass of 10^7.8M_⊙, a star formation rate of 0.96_−0.26^+0.47M_⊙yr⁻¹, and a metallicity of ∼0.2 Z_⊙. 

Abstract We present photometric and spectroscopic data for SN 2022joj, a nearby peculiar Type Ia supernova (SN Ia) with a fast decline rate (Δm_15,B= 1.4 mag). SN 2022joj shows exceedingly red colors, with a value of approximatelyB−V≈ 1.1 mag during its initial stages, beginning from 11 days before maximum brightness. As it evolves, the flux shifts toward the blue end of the spectrum, approachingB−V≈ 0 mag around maximum light. Furthermore, at maximum light and beyond, the photometry is consistent with that of typical SNe Ia. This unusual behavior extends to its spectral characteristics, which initially displayed a red spectrum and later evolved to exhibit greater consistency with typical SNe Ia. Spectroscopically, we find strong agreement between SN 2022joj and double detonation models with white dwarf masses of around 1M_⊙and a thin He shell between 0.01 and 0.05M_⊙. Moreover, the early red colors are explained by line-blanketing absorption from iron peak elements created by the double detonation scenario in similar mass ranges. The nebular spectra in SN 2022joj deviate from expectations for double detonation, as we observe strong [Feiii] emission instead of [Caii] lines as anticipated, though this is not as robust a prediction as early red colors and spectra. The fact that as He shells get thinner these SNe start to look more like normal SNe Ia raises the possibility that this is the triggering mechanism for the majority of SNe Ia, though evidence would be missed if the SNe are not observed early enough. 

ABSTRACT Photometric and spectroscopic data for two Low Luminosity Type IIP Supernovae (LL SNe IIP) 2020cxd and 2021aai are presented. SN 2020cxd was discovered 2 d after explosion at an absolute magnitude of Mr  = −14.02 ± 0.21 mag, subsequently settling on a plateau which lasts for ∼120 d. Through the luminosity of the late light curve tail, we infer a synthesized 56Ni mass of (1.8 ± 0.5) × 10−3 M⊙. During the early evolutionary phases, optical spectra show a blue continuum ($$T\, \gt $$8000 K) with broad Balmer lines displaying a P Cygni profile, while at later phases, Ca ii, Fe ii, Sc ii, and Ba ii lines dominate the spectra. Hydrodynamical modelling of the observables yields $$R\, \simeq$$ 575 R⊙ for the progenitor star, with Mej  = 7.5 M⊙ and $$E\, \simeq$$ 0.097 foe emitted during the explosion. This low-energy event originating from a low-mass progenitor star is compatible with both the explosion of a red supergiant (RSG) star and with an Electron Capture Supernova arising from a super asymptotic giant branch star. SN 2021aai reaches a maximum luminosity of Mr  = −16.57 ± 0.23 mag (correcting for AV = 1.92 mag), at the end of its remarkably long plateau (∼140 d). The estimated 56Ni mass is (1.4 ± 0.5) × 10−2 M⊙. The expansion velocities are compatible with those of other LL SNe IIP (few 103 km s−1). The physical parameters obtained through hydrodynamical modelling are $$R\, \simeq$$ 575 R⊙, Mej = 15.5 M⊙, and E = 0.4 foe. SN 2021aai is therefore interpreted as the explosion of an RSG, with properties that bridge the class of LL SNe IIP with standard SN IIP events. 

ABSTRACT We present an in-depth study of the late-time near-infrared plateau in Type Ia supernovae (SNe Ia), which occurs between 70 and 500 d. We double the existing sample of SNe Ia observed during the late-time near-infrared plateau with new observations taken with the Hubble Space Telescope, Gemini, New Technology Telescope, the 3.5-m Calar Alto Telescope, and the Nordic Optical Telescope. Our sample consists of 24 nearby SNe Ia at redshift < 0.025. We are able to confirm that no plateau exists in the Ks band for most normal SNe Ia. SNe Ia with broader optical light curves at peak tend to have a higher average brightness on the plateau in J and H, most likely due to a shallower decline in the preceding 100 d. SNe Ia that are more luminous at peak also show a steeper decline during the plateau phase in H. We compare our data to state-of-the-art radiative transfer models of nebular SNe Ia in the near-infrared. We find good agreement with the sub-Mch model that has reduced non-thermal ionization rates, but no physical justification for reducing these rates has yet been proposed. An analysis of the spectral evolution during the plateau demonstrates that the ratio of [Fe ii] to [Fe iii] contribution in a near-infrared filter determines the light curve evolution in said filter. We find that overluminous SNe decline slower during the plateau than expected from the trend seen for normal SNe Ia. 

Abstract We present a sample of Type Icn supernovae (SNe Icn), a newly discovered class of transients characterized by their interaction with H- and He-poor circumstellar material (CSM). This sample is the largest collection of SNe Icn to date and includes observations of two published objects (SN 2019hgp and SN 2021csp) and two objects not yet published in the literature (SN 2019jc and SN 2021ckj). The SNe Icn display a range of peak luminosities, rise times, and decline rates, as well as diverse late-time spectral features. To investigate their explosion and progenitor properties, we fit their bolometric light curves to a semianalytical model consisting of luminosity inputs from circumstellar interaction and radioactive decay of⁵⁶Ni. We infer low ejecta masses (≲2M_⊙) and⁵⁶Ni masses (≲0.04M_⊙) from the light curves, suggesting that normal stripped-envelope supernova (SESN) explosions within a dense CSM cannot be the underlying mechanism powering SNe Icn. Additionally, we find that an estimate of the star formation rate density at the location of SN 2019jc lies at the lower end of a distribution of SESNe, in conflict with a massive star progenitor of this object. Based on its estimated ejecta mass,⁵⁶Ni mass, and explosion site properties, we suggest a low-mass, ultra-stripped star as the progenitor of SN 2019jc. For other SNe Icn, we suggest that a Wolf–Rayet star progenitor may better explain their observed properties. This study demonstrates that multiple progenitor channels may produce SNe Icn and other interaction-powered transients.