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  1. Free, publicly-accessible full text available June 1, 2024
  2. null (Ed.)
    ABSTRACT Ce-based intermetallics are of interest due to the potential to study the interplay of localized magnetic moments and conduction electrons. Our work on Ce-based germanides led to the identification of a new homologous series An+1MnX3n+1 (A = rare earth, M = transition metal, X = tetrels, and n = 1–6). This work presents the single-crystal growth, structure determination, and anisotropic magnetic properties of the n = 4 member of the Cen+1ConGe3n+1 homologous series. Ce5Co4+xGe13−ySny consists of three Ce sites, three Co sites, seven Ge sites, and two Sn sites, and the crystal structure is best modeled in the orthorhombic space group Cmmm where a = 4.3031(8) Å, b = 45.608(13) Å, and c = 4.3264(8) Å, which is in close agreement with the previously reported Sn-free analog where a = 4.265(1) Å, b = 45.175(9) Å, and c = 4.293(3) Å. Anisotropic magnetic measurements show Kondo-like behavior and three magnetic transitions at 6, 4.9, and 2.4 K for Ce5Co4+xGe13−ySn 
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  3. Abstract

    CeOs4Sb12, a member of the skutterudite family, has an unusual semimetallic low-temperatureL-phase that inhabits a wedge-like area of the fieldH—temperatureTphase diagram. We have conducted measurements of electrical transport and megahertz conductivity on CeOs4Sb12single crystals under pressures of up to 3 GPa and in high magnetic fields of up to 41 T to investigate the influence of pressure on the differentHTphase boundaries. While the high-temperature valence transition between the metallicH-phase and theL-phase is shifted to higherTby pressures of the order of 1 GPa, we observed only a marginal suppression of theS-phase that is found below 1 K for pressures of up to 1.91 GPa. High-field quantum oscillations have been observed for pressures up to 3.0 GPa and the Fermi surface of the high-field side of theH-phase is found to show a surprising decrease in size with increasing pressure, implying a change in electronic structure rather than a mere contraction of lattice parameters. We evaluate the field-dependence of the effective masses for different pressures and also reflect on the sample dependence of some of the properties of CeOs4Sb12which appears to be limited to the low-field region.

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  4. null (Ed.)
  5. Abstract

    High entropy alloys (HEA) are an unusual class of materials where mixtures of elements are stochastically arrayed on a simple crystalline lattice. These systems exhibit remarkable functionality, often along several distinct axes: e.g., the examples [TaNb]1-x(TiZrHf)xare high strength and damage resistant refractory metals that also exhibit superconductivity with large upper critical fields. Here we report the discovery of anf-electron containing HEA, [TaNb]0.31(TiUHf)0.69, which is the first to include an actinide ion. Similar to the Zr-analogue, this material crystallizes in a body-centered cubic lattice with the lattice constanta = 3.41(1) Å and exhibits phonon mediated superconductivity with a transition temperaturesTc ≈ 3.2 K and upper critical fieldsHc2 ≈ 6.4 T. These results expand this class of materials to include actinide elements, shows that superconductivity is robust in this sub-group, and opens the path towards leveraging HEAs as functional waste forms for a variety of radioisotopes.

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