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Investigations of Bis(alkylthiocarbamato)copper Linkage Isomers

https://doi.org/10.1021/acs.inorgchem.2c00371

Bajaj, Kritika ; Andres, Sarah A. ; Hofsommer, Dillon T. ; Galib, Mirza ; Mashuta, Mark S. ; Bennett, Brian ; Narayanan, Badri ; Buchanan, Robert M. ; Bates, Paula J. ; Grapperhaus, Craig A. ( May 2022 , Inorganic Chemistry)

Free, publicly-accessible full text available May 23, 2023
Antifungal activity of thiosemicarbazones, bis(thiosemicarbazones), and their metal complexes

https://doi.org/10.1016/j.jinorgbio.2021.111620

Bajaj, Kritika ; Buchanan, Robert M. ; Grapperhaus, Craig A. ( December 2021 , Journal of Inorganic Biochemistry)

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The pH and Potential Dependence of Pb‐Catalyzed Electrochemical CO ₂ Reduction to Methyl Formate in a Dual Methanol/Water Electrolyte

https://doi.org/10.1002/cssc.202102289

Hofsommer, Dillon T. ; Liang, Ying ; Uttarwar, Sandesh S. ; Gautam, Manu ; Pishgar, Sahar ; Gulati, Saumya ; Grapperhaus, Craig A. ; Spurgeon, Joshua M. ( March 2022 , ChemSusChem)

Free, publicly-accessible full text available March 8, 2023
Small molecule crystals with 1D water wires modulate electronic properties of surface water networks

https://doi.org/10.1016/j.apmt.2020.100895

Saraei, Nina ; Gupta, Alexander J. ; Hietsoi, Oleksandr ; Frye, Brian C. ; Hofsommer, Dillon T. ; Sumanasekera, Gamini ; Gupta, Gautam ; Mashuta, Mark S. ; Buchanan, Robert M. ; Grapperhaus, Craig A. ( March 2021 , Applied Materials Today)

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Copper bis(thiosemicarbazone) Complexes with Pendent Polyamines: Effects of Proton Relays and Charged Moieties on Electrocatalytic HER

https://doi.org/10.1002/ejic.202000774

Calvary, Caleb A. ; Hietsoi, Oleksandr ; Hofsommer, Dillon T. ; Brun, Henry C. ; Costello, Alison M. ; Mashuta, Mark S. ; Spurgeon, Joshua M. ; Buchanan, Robert M. ; Grapperhaus, Craig A. ( January 2021 , European Journal of Inorganic Chemistry)

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Electrocatalytic Hydrogen Evolution and Oxidation with Rhenium Tris(thiolate) Complexes: A Competition between Rhenium and Sulfur for Electrons and Protons

https://doi.org/10.1021/acscatal.9b04579

Tang, Hao ; Brothers, Edward N. ; Grapperhaus, Craig A. ; Hall, Michael B. ( March 2020 , ACS Catalysis)

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Exploiting Metal–Ligand Cooperativity to Sequester, Activate, and Reduce Atmospheric Carbon Dioxide with a Neutral Zinc Complex

https://doi.org/10.1021/acs.inorgchem.0c00121

Cronin, Steve P. ; Strain, Jacob M. ; Mashuta, Mark S. ; Spurgeon, Joshua M. ; Buchanan, Robert M. ; Grapperhaus, Craig A. ( April 2020 , Inorganic Chemistry)

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Synthesis, Characterization, and Biological Activity of Hybrid Thiosemicarbazone–Alkylthiocarbamate Metal Complexes

https://doi.org/10.1021/acs.inorgchem.0c00182

Andres, Sarah A. ; Bajaj, Kritika ; Vishnosky, Nicholas S. ; Peterson, Megan A. ; Mashuta, Mark S. ; Buchanan, Robert M. ; Bates, Paula J. ; Grapperhaus, Craig A. ( April 2020 , Inorganic Chemistry)

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Utilizing Charge Effects and Minimizing Intramolecular Proton Rearrangement to Improve the Overpotential of a Thiosemicarbazonato Zinc HER Catalyst

https://doi.org/10.1021/acs.inorgchem.9b01912

Cronin, Steve P. ; Mamun, Abdullah Al ; Toda, Megan J. ; Mashuta, Mark S. ; Losovyj, Yaroslav ; Kozlowski, Pawel M. ; Buchanan, Robert M. ; Grapperhaus, Craig A. ( September 2019 , Inorganic Chemistry)

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Photocatalytic hydrogen evolution on Si photocathodes modified with bis(thiosemicarbazonato)nickel( ii )/Nafion

https://doi.org/10.1039/c9cc04117f

Gulati, Saumya ; Hietsoi, Oleksandr ; Calvary, Caleb A. ; Strain, Jacob M. ; Pishgar, Sahar ; Brun, Henry C. ; Grapperhaus, Craig A. ; Buchanan, Robert M. ; Spurgeon, Joshua M. ( August 2019 , Chemical Communications)

The molecular catalyst diacetyl-bis( N -4-methyl-3-thiosemi-carbazonato)nickel( ii ) (NiATSM) was integrated with Si for light-driven hydrogen evolution from water. Compared to an equivalent loading of Ni metal, the NiATSM/p-Si electrode performed better. Durability of the surface-bound catalyst under operation in acid was achieved without covalent attachment by using Nafion binding.

Full Text Available

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