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Single-chain polymer nanoparticle photoredox catalysts are designed wherein spatial proximity enables the crosslinking acene to act as a redox mediator, thus achieving up to 30-fold enhancement of catalyst activity in the model Diels–Alder reaction.more » « lessFree, publicly-accessible full text available May 7, 2025
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Huss, Steven; Walsh, Andrew R.; Griggs, Anna; Rodriguez-Acevedo, Diego Alejandro; Arias-Rotondo, Daniela M.; Elacqua, Elizabeth (, Polymer Chemistry)We present a [Ru(bpy)2(dmbpy)]2+- and pyrene-based photocatalytic PMMA that enables photoredox-energy transfer to achieve the C–H arylation of electron deficient aryl bromides.more » « less