Search for: All records

Atmospheric ammonia (NH3), primarily emitted from agriculture, poses significant threats to ecosystems, climate, and human health through nitrogen deposition and secondary aerosol formation. NH3 flux estimates remain highly uncertain due to limited direct observations and complex emission–deposition processes. Here, we estimated NH3 fluxes over the contiguous United States using satellite observations from the Infrared Atmospheric Sounding Interferometer (IASI, 2008–2022) and Cross-track Infrared Sounder (CrIS, 2012–2022) by applying a directional derivative approach. Our results highlight major agricultural emission hotspots, including the San Joaquin Valley in California, the Snake River Valley in Idaho, the Texas panhandle, the Great Plains, Southeastern Pennsylvania, and Eastern North Carolina. NH3 removal is predominantly driven by deposition near source areas rather than chemical transformation, with strong sinks in vegetation-dense regions such as forests, grasslands, shrublands, and wetlands. Seasonal flux variations show peaks in warm months and lower values in winter, driven by temperature-dependent volatilization from livestock production and fertilizer application. Compared with bottom-up inventory, satellite-based estimates capture general spatial and seasonal patterns, while also revealing additional insights into key flux hotspots and peak periods. CrIS consistently reports higher fluxes than IASI, especially in spring, reflecting differences in their overpass times. Combining IASI (morning overpass) and CrIS (midday overpass) observations enables a better understanding of diurnal NH3 flux dynamics. These findings provide critical insights into NH3 spatiotemporal variabilities, complementing inventory-based approaches and informing nitrogen management and environmental policy, particularly in regions with limited ground-based monitoring. 

Abstract Atmospheric dryness (i.e., high vapor pressure deficit, VPD), together with soil moisture stress, limits plant photosynthesis and threatens ecosystem functioning. Regions where rainfall and soil moisture are relatively sufficient, such as the rainfed part of the U.S. Corn Belt, are especially prone to high VPD stress. With globally projected rising VPD under climate change, it is crucial to understand, simulate, and manage its negative impacts on agricultural ecosystems. However, most existing models simulating crop response to VPD are highly empirical and insufficient in capturing plant response to high VPD, and improved modeling approaches are urgently required. In this study, by leveraging recent advances in plant hydraulic theory, we demonstrate that the VPD constraints in the widely used coupled photosynthesis‐stomatal conductance models alone are inadequate to fully capture VPD stress effects. Incorporating plant xylem hydraulic transport significantly improves the simulation of transpiration under high VPD, even when soil moisture is sufficient. Our results indicate that the limited water transport capability from the plant root to the leaf stoma could be a major mechanism of plant response to high VPD stress. We then introduce a Demand‐side Hydraulic Limitation Factor (DHLF) that simplifies the xylem and the leaf segments of the plant hydraulic model to only one parameter yet captures the effect of plant hydraulic transport on transpiration response to high VPD with similar accuracy. We expect the improved understanding and modeling of crop response to high VPD to help contribute to better management and adaptation of agricultural systems in a changing climate.