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Al-V alloys produced via high-energy ball milling have been reported to show simultaneous improvement of corrosion resistance and mechanical properties compared to traditional Al alloys. In these alloys, V content plays a crucial role in increasing or decreasing the corrosion resistance. Therefore, the effect of V and microstructure on corrosion of high-energy ball milled and subsequently spark plasma sintered Al-xV alloys (x = 2, 5, 10 at%) has been studied. Cyclic potentiodynamic polarization tests and electrochemical impedance spectroscopic analysis revealed the increment of V content up to 5 at% enhanced the corrosion resistance of the alloy. However, highly heterogeneous microstructure in Al-10 at%V resulted in significant localized corrosion over the immersion time. The electrochemical impedance spectroscopy studies over 14 days of immersion revealed underlying corrosion mechanisms.

The time-dependent corrosion behavior of pure aluminum (Al) in a chloride-containing environment was investigated using various electrochemical and characterization techniques for up to 336 h. Transmission electron microscopic and secondary ion mass spectroscopic analysis revealed the continuous dissolution of the surface film over the immersion time. In the meantime, the increasing passive oxide thickness resulted in the surface film resistance enhancement over the immersion time, as indicated by the electrochemical impedance spectroscopic analysis. The electrochemical noise measurements showed an increase in the corrosion kinetics with immersion time until 60 h because of the accelerated localized corrosion in the early stage of immersion. However, an inhibition in corrosion kinetics occurred after longer immersion times due to corrosion product deposition inside the pit.

Context.Dark gamma-ray bursts (GRBs) constitute a significant fraction of the GRB population. In this paper, we present a multi-wavelength analysis (both prompt emission and afterglow) of an intense (3.98  ×  10⁻⁵erg cm⁻²usingFermi-Gamma-Ray Burst Monitor) two-episodic GRB 150309A observed early on until ∼114 days post burst. Despite the strong gamma-ray emission, no optical afterglow was detected for this burst. However, we discovered near-infrared (NIR) afterglow (K_S-band), ∼5.2 h post burst, with the CIRCE instrument mounted at the 10.4 m Gran Telescopio Canarias (hereafter, GTC).

Aims.We aim to examine the characteristics of GRB 150309A as a dark burst and to constrain other properties using multi-wavelength observations.

Methods.We usedFermiobservations of GRB 150309A to understand the prompt emission mechanisms and jet composition. We performed early optical observations using the BOOTES robotic telescope and late-time afterglow observations using the GTC. A potential faint host galaxy was also detected in the optical wavelength using the GTC. We modelled the potential host galaxy of GRB 150309A in order to explore the environment of the burst.

Results.The time-resolved spectral analysis ofFermidata indicates a hybrid jet composition consisting of a matter-dominated fireball and magnetic-dominated Poynting flux. The GTC observations of the afterglow revealed that the counterpart of GRB 150309A was very red, withH − K_S > 2.1 mag (95% confidence). The red counterpart was not discovered in any bluer filters ofSwiftUVOT/BOOTES, which would be indicative of a high redshift origin. Therefore we discarded this possibility based on multiple arguments, such as spectral analysis of the X-ray afterglow constrainz < 4.15 and a moderate redshift value obtained using the spectral energy distribution (SED) modelling of the potential galaxy. The broadband (X-ray to NIR bands) afterglow SED implies a very dusty host galaxy with a deeply embedded GRB (suggestingA_V ≳ 35 mag).

Conclusions.The environment of GRB 150309A demands a high extinction towards the line of sight. Demanding dust obscuration is the most probable origin of optical darkness as well as the very red afterglow of GRB 150309A. This result establishes GRB 150309A as the most extinguished GRB known to date.

Nanocrystalline supersaturated Al-V alloys produced by high-energy ball milling have been reported to exhibit enhanced corrosion resistance and mechanical properties compared to commercial Al alloys. Corrosion of passive alloys such as Al-V alloy relies on the characteristics of the surface film, which is studied using scanning/transmission electron microscopy and time-of-flight secondary ion mass spectrometry. The effect of microstructure and composition on the surface film has been investigated after different immersion periods (30 min, 2 h, and 1 day) in 0.1 M NaCl. The surface film was complex and composed of oxidized Al and V. The heterogeneous surface film was observed due to the presence of secondary phases and initiation of localized corrosion. The void formation was observed beneath the surface film that would potentially cause pitting corrosion. The generation of nano-sized voids was dependent on grain orientation. Compared to pure Al, the chloride penetration is suppressed in Al-V alloys. The effect of composition and microstructure on surface film formation and attendant corrosion behavior is discussed herein.