Search for: All records

A photoinduced functionalization and defunctionalization of alkyl halides using Hünig's base (diisopropylethylamine) is presented. This protocol successfully reduces, chalcogenates, and borylates a broad range of aliphatic halides. 

Context.The archetypal blazar 3C 279 has a prominent relativistic jet and strong broadband variability across the electromagnetic spectrum. In April 2017, the Event Horizon Telescope (EHT) observed 3C 279 with an unprecedented angular resolution of about 20 μas, accompanied by one of the most extensive quasi-simultaneous multiwavelength (MWL) campaigns ever conducted, spanning from radio to TeVγ-ray energies. Aims.Taking advantage of this comprehensive MWL dataset, we investigated the physical processes governing 3C 279, with a particular focus on the formation, collimation, and acceleration of its relativistic jet and on the origin of its high-energy emission, including the underlying particle-acceleration mechanisms. Methods.We analyzed individual observations and multiband light curves. We also constructed a new quasi-simultaneous spectral energy distribution covering frequencies from the radio band to very high-energy (VHE)γrays. We further performed a phenomenological modeling using the turbulent extreme multi-zone (TEMZ) model to constrain the fundamental physical properties of the source. Results.The EHT observations reveal a clear flux increase in the innermost core between April 5 and 11, 2017. Over a broader time span, radio observations at longer wavelengths reveal concurrent enhancements in the core flux and polarization around mid-April, coinciding with the ejection of a superluminal knot moving at (25 ± 2)c. Record UV–optical flares with strong polarization variability occurred in late March, followed by high-energyγ-ray activity that declined before the end of the EHT observing period. During this time, the source remained in a low X-ray state and exhibited no detectable VHE emission. Conclusions.The results of the TEMZ modeling indicate that the broadband spectrum and variability of 3C 279 might be explained with a jet scenario in which turbulent plasma cells are compressed by a stationary conical shock. Nonetheless, alternative interpretations, such as magnetic reconnection or a moving shock-in-jet event, remain possible. This coordinated MWL campaign advances our understanding of the origin of the jet andγ-ray emission in the blazar 3C 279, and it also provides a comprehensive publicly available dataset that will serve as a valuable reference for future studies. 

Bulk sediment chemistry was measured at 2 cm resolution along cores from International Ocean Discovery Program (IODP) Site U1457 using the X-ray fluorescence (XRF) core scanner at the IODP Gulf Coast Repository. The Pleistocene splice section assembled from Holes U1457A and U1457B was scanned in its entirety, and nearly continuous sediment bulk chemistry profiles were constructed to a depth of 125 m core composite depth below seafloor (CCSF). Some sections of Hole U1457C were also scanned: (1) an upper Miocene hemipelagic section and (2) a 30 m lower Paleocene section directly overlying basalt. In the Pleistocene spliced sections, 2 cm spacing represents a sampling resolution of 150–300 y, whereas in the upper Miocene section this spacing represents about 500 y between samples. We report data and acquisition conditions for major and many minor elements. We find large variability in CaCO3 content in the Pleistocene section, from around 14 to 89 wt%. We used discrete shipboard CaCO3 measurements to calibrate the XRF Ca data. CaCO3 has cyclic variability and correlates with light sediment colors. Variation in aluminosilicate elements is largely caused by changes in dilution by CaCO3. The lower part of the spliced section, presumably representing distal Indus Fan deposits, has a distinctive but more uniform composition than the upper part. 

Abstract The detection of gravitational waves (GWs) from a binary neutron star (BNS) merger by Advanced LIGO and Advanced Virgo (GW170817), together with its electromagnetic counterpart, the short gamma-ray burst GRB 170817A, heralded the birth of multimessenger astronomy. The detection of TeV emission from GRBs motivates follow-up observations with the Cherenkov Telescope Array Observatory (CTAO), which is ideal for detecting such signals due to its unprecedented sensitivity, rapid response, and wide-field survey capabilities. The aim of this work is to evaluate GeV–TeV GW follow-up strategies for CTAO using a multistep simulation pipeline and to estimate the expected rate of joint GW–GRB detections during observing run O5. Using a simulated sample of BNS systems with corresponding GW detections, gamma-ray emission is simulated through phenomenological prescriptions based on the observed population of short GRBs, including off-axis jet scenarios. CTAO observations are simulated to account for instrument response, sky tiling strategies, integration times, and varying observing conditions. Strategies with variable and constant integration times are investigated. We find that, via an optimized follow-up strategy, about 5% of simulated GW-associated short GRBs produce GeV–TeV radiation detectable by CTAO. Detectability is strongly influenced by the jet opening angle and viewing angle, suggesting that even rough estimates of the viewing angle in GW alerts could enhance targeting. This framework motivates future follow-ups of GW-detectable events, including neutron star–black hole mergers, and further supports the development of advanced strategies incorporating galaxy distributions and synergies with future detectors such as the Einstein Telescope. 

We present the measurement of ${\pi }^{+}$ -argon inelastic cross sections using the ProtoDUNE single-phase liquid argon time projection chamber in the incident ${\pi }^{+}$ kinetic energy range of 500–800 MeV in multiple exclusive channels (absorption, charge exchange, and the remaining inelastic interactions). The results of this analysis are important inputs to simulations of liquid argon neutrino experiments such as the Deep Underground Neutrino Experiment and the Short Baseline Neutrino program at Fermi National Accelerator Laboratory. They will be employed to improve the modeling of final state interactions within neutrino event generators used by these experiments, as well as the modeling of ${\pi }^{+}$ -argon secondary interactions within the liquid argon. This is the first measurement of ${\pi }^{+}$ -argon absorption at this kinetic energy range as well as the first ever measurement of ${\pi }^{+}$ -argon charge exchange. 

Abstract Dwarf spheroidal galaxies (dSphs) are excellent targets for indirect dark matter (DM) searches using gamma-ray telescopes because they are thought to have high DM content and a low astrophysical background. The sensitivity of these searches is improved by combining the observations of dSphs made by different gamma-ray telescopes. We present the results of a combined search by the most sensitive currently operating gamma-ray telescopes, namely: the satellite-borneFermi-LAT telescope; the ground-based imaging atmospheric Cherenkov telescope arrays H.E.S.S., MAGIC, and VERITAS; and the HAWC water Cherenkov detector. Individual datasets were analyzed using a common statistical approach. Results were subsequently combined via a global joint likelihood analysis. We obtain constraints on the velocity-weighted cross section 〈σv〉 for DM self-annihilation as a function of the DM particle mass. This five-instrument combination allows the derivation of up to 2-3 times more constraining upper limits on 〈σv〉 than the individual results over a wide mass range spanning from 5 GeV to 100 TeV. Depending on the DM content modeling, the 95% confidence level observed limits reach 1.5×10^-24 cm³s^-1and 3.2×10^-25 cm³s^-1, respectively, in theτ⁺τ^-annihilation channel for a DM mass of 2 TeV. 

The 2x2 Demonstrator, a prototype for the Deep Underground Neutrino Experiment (DUNE) liquid argon (LAr) Near Detector, was exposed to the Neutrinos from the Main Injector (NuMI) neutrino beam at Fermi National Accelerator Laboratory (Fermilab). This detector is a prototype of a new modular design for a liquid argon time-projection chamber (LArTPC), comprising a two-by-two array of four modules, each further segmented into two optically isolated LArTPCs. The 2x2 Demonstrator features a number of pioneering technologies, including a low-profile resistive field shell to establish drift fields, native 3D ionization pixelated imaging, and a high-coverage dielectric light readout system. The 2.4-tonne active mass detector is flanked upstream and downstream by supplemental solid-scintillator tracking planes, repurposed from the MINERvA experiment, which track ionizing particles exiting the argon volume. The antineutrino beam data collected by the detector over a 4.5 day period in 2024 include over 30,000 neutrino interactions in the LAr active volume—the first neutrino interactions reported by a DUNE detector prototype. During its physics-quality run, the 2x2 Demonstrator operated at a nominal drift field of 500 V/cm and maintained good LAr purity, with a stable electron lifetime of approximately 1.25 ms. This paper describes the detector and supporting systems, summarizes the installation and commissioning, and presents the initial validation of collected NuMI beam and off-beam self-triggers. In addition, it highlights observed interactions in the detector volume, including candidate muon antineutrino events. 

The Deep Underground Neutrino Experiment (DUNE) is a next-generation neutrino experiment with a rich physics program that includes searches for the hypothetical phenomenon of proton decay. Utilizing liquid-argon time-projection chamber technology, DUNE is expected to achieve world-leading sensitivity in the proton decay channels that involve charged kaons in their final states. The first DUNE demonstrator, ProtoDUNE Single-Phase, was a 0.77 kt detector that operated from 2018 to 2020 at the CERN Neutrino Platform, exposed to a mixed hadron and electron test-beam with momenta ranging from 0.3 to $7\mathrm{GeV}/\mathrm{c}$ . We present a selection of low-energy kaons among the secondary particles produced in hadronic reactions, using data from the 6 and $7\mathrm{GeV}/\mathrm{c}$ beam runs. The selection efficiency is 1% and the sample purity 92%. The initial energies of the selected kaon candidates encompass the expected energy range of kaons originating from proton decay events in DUNE (below $\sim 200\mathrm{MeV}$ ). In addition, we demonstrate the capability of this detector technology to discriminate between kaons and other particles such as protons and muons, and provide a comprehensive description of their energy loss in liquid argon, which shows good agreement with the simulation. These results pave the way for future proton decay searches at DUNE. 

Aims.Mrk 421 was in its most active state around early 2010, which led to the highest TeV gamma-ray flux ever recorded from any active galactic nuclei (AGN). We aim to characterize the multiwavelength behavior during this exceptional year for Mrk 421, and evaluate whether it is consistent with the picture derived with data from other less exceptional years. Methods.We investigated the period from November 5, 2009, (MJD 55140) until July 3, 2010, (MJD 55380) with extensive coverage from very-high-energy (VHE;E > 100 GeV) gamma rays to radio with MAGIC, VERITAS,Fermi-LAT,RXTE,Swift, GASP-WEBT, VLBA, and a variety of additional optical and radio telescopes. We characterized the variability by deriving fractional variabilities as well as power spectral densities (PSDs). In addition, we investigated images of the jet taken with VLBA and the correlation behavior among different energy bands. Results.Mrk 421 was in widely different states of activity throughout the campaign, ranging from a low-emission state to its highest VHE flux ever recorded. We find the strongest variability in X-rays and VHE gamma rays, and PSDs compatible with power-law functions with indices around 1.5. We observe strong correlations between X-rays and VHE gamma rays at zero time lag with varying characteristics depending on the exact energy band. We also report a marginally significant (∼3σ) positive correlation between high-energy (HE;E > 100 MeV) gamma rays and the ultraviolet band. We detected marginally significant (∼3σ) correlations between the HE and VHE gamma rays, and between HE gamma rays and the X-ray, that disappear when the large flare in February 2010 is excluded from the correlation study, hence indicating the exceptionality of this flaring event in comparison with the rest of the campaign. The 2010 violent activity of Mrk 421 also yielded the first ejection of features in the VLBA images of the jet of Mrk 421. Yet the large uncertainties in the ejection times of these unprecedented radio features prevent us from firmly associating them to the specific flares recorded during the 2010 campaign. We also show that the collected multi-instrument data are consistent with a scenario where the emission is dominated by two regions, a compact and extended zone, which could be considered as a simplified implementation of an energy-stratified jet as suggested by recentIXPEobservations. 

ABSTRACT OT 081 is a well-known, luminous blazar that is remarkably variable in many energy bands. We present the first broadband study of the source, which includes very high energy (VHE, $$E\gt $$ 100 GeV) $$\gamma$$-ray data taken by the MAGIC (Major Atmospheric Gamma-ray Imaging Cherenkov telescopes) and H.E.S.S. (High Energy Stereoscopic System) imaging Cherenkov telescopes. The discovery of VHE $$\gamma$$-ray emission happened during a high state of $$\gamma$$-ray activity in July 2016, observed by many instruments from radio to VHE $$\gamma$$-rays. We identify four states of activity of the source, one of which includes VHE $$\gamma$$-ray emission. Variability in the VHE domain is found on daily time-scales. The intrinsic VHE spectrum can be described by a power law with index $$3.27\pm 0.44_{\rm stat}\pm 0.15_{\rm sys}$$ (MAGIC) and $$3.39\pm 0.58_{\rm stat}\pm 0.64_{\rm sys}$$ (H.E.S.S.) in the energy range of 55–300 and 120–500 GeV, respectively. The broadband emission cannot be successfully reproduced by a simple one-zone synchrotron self-Compton model. Instead, an additional external Compton component is required. We test a lepto-hadronic model that reproduces the data set well and a proton-synchrotron-dominated model that requires an extreme proton luminosity. Emission models that are able to successfully represent the data place the emitting region well outside of the broad-line region to a location at which the radiative environment is dominated by the infrared thermal radiation field of the dusty torus. In the scenario described by this flaring activity, the source appears to be a flat spectrum radio quasar (FSRQ), in contrast with past categorizations. This suggests that the source can be considered to be a transitional blazar, intermediate between BL Lac and FSRQ objects.