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X-ray fluorescence (XRF) core scanning was conducted on core sections from International Ocean Discovery Program Site U1474, located in the Natal Valley off the coast of South Africa. The data were collected at 2 mm resolution along the 255 m length of the splice, but this setting resulted in noisy data. This problem was addressed by applying a 10 point running sum on the XRF data prior to converting peak area to element intensities. This effectively integrates 10 measurements into 1, representing an average over 2 cm resolution, and significantly improves noise in the data. With 25 calibration samples, whose element concentrations were derived using inductively coupled plasma–optical emission spectrometry, the XRF measurements were converted to concentrations using a univariate log-ratio calibration method. The resulting concentrations of terrigenously derived major elements (Al, Si, K, Ti, and Fe) are anticorrelated with Ca concentrations, indicating the main control on sediment chemistry is the variable proportion of terrigenous to in situ produced carbonate material.

International Ocean Discovery Program Expedition 361 drilled six sites on the southeast African margin (southwest Indian Ocean) and in the Indian-Atlantic Ocean gateway, from 30 January to 31 March 2016. In total, 5175 m of core was recovered, with an average recovery of 102%, during 29.7 days of on-site operations. The sites, situated in the Mozambique Channel at locations directly influenced by discharge from the Zambezi and Limpopo River catchments, the Natal Valley, the Agulhas Plateau, and Cape Basin, were targeted to reconstruct the history of the greater Agulhas Current system over the past ~5 My. The Agulhas Current is the strongest western boundary current in the Southern Hemisphere, transporting some 70 Sv of warm, saline surface water from the tropical Indian Ocean along the East African margin to the tip of Africa. Exchanges of heat and moisture with the atmosphere influence southern African climates, including individual weather systems such as extratropical cyclone formation in the region and rainfall patterns. Recent ocean model and paleoceanographic data further point at a potential role of the Agulhas Current in controlling the strength and mode of the Atlantic Meridional Overturning Circulation (AMOC) during the Late Pleistocene. Spillage of saline Agulhas water into themore »South Atlantic stimulates buoyancy anomalies that may influence basin-wide AMOC, with implications for convective activity in the North Atlantic and global climate change. The main objectives of the expedition were to establish the role of the Agulhas Current in climatic changes during the Pliocene–Pleistocene, specifically to document the dynamics of the Indian-Atlantic Ocean gateway circulation during this time, to examine the connection of the Agulhas leakage and AMOC, and to address the influence of the Agulhas Current on African terrestrial climates and coincidences with human evolution. Additionally, the expedition set out to fulfill the needs of Ancillary Project Letter number 845, consisting of high-resolution interstitial water sampling to help constrain the temperature and salinity profiles of the ocean during the Last Glacial Maximum. The expedition made major strides toward fulfilling each of these objectives. The recovered sequences allowed generation of complete spliced stratigraphic sections that range from 0 to between ~0.13 and 7 Ma. This sediment will provide decadal- to millennial-scale climatic records that will allow answering the paleoceanographic and paleoclimatic questions set out in the drilling proposal.« less

International Ocean Discovery Program (IODP) Expedition 361 drilled six sites on the southeast African margin and in the Indian-Atlantic ocean gateway, southwest Indian Ocean, from 30 January to 31 March 2016. In total, 5175 m of core was recovered, with an average recovery of 102%, during 29.7 days of on-site operations. The sites, situated in the Mozambique Channel at locations directly influenced by discharge from the Zambezi and Limpopo River catchments, the Natal Valley, the Agulhas Plateau, and Cape Basin, were targeted to reconstruct the history of the greater Agulhas Current system over the past ~5 my. The Agulhas Current is the strongest western boundary current in the Southern Hemisphere, transporting some 70 Sv of warm, saline surface water from the tropical Indian Ocean along the East African margin to the tip of Africa. Exchanges of heat and moisture with the atmosphere influence southern African climates, including individual weather systems such as extratropical cyclone formation in the region and rainfall patterns. Recent ocean model and paleoceanographic data further point at a potential role of the Agulhas Current in controlling the strength and mode of the Atlantic Meridional Overturning Circulation (AMOC) during the Late Pleistocene. Spillage of saline Agulhas water intomore »the South Atlantic stimulates buoyancy anomalies that act as control mechanisms on the basin-wide AMOC, with implications for convective activity in the North Atlantic and global climate change. The main objectives of the expedition were to establish the sensitivity of the Agulhas Current to climatic changes during the Pliocene–Pleistocene, to determine the dynamics of the Indian-Atlantic gateway circulation during this time, to examine the connection of the Agulhas leakage and AMOC, and to address the influence of the Agulhas Current on African terrestrial climates and coincidences with human evolution. Additionally, the expedition set out to fulfill the needs of the Ancillary Project Letter, consisting of high-resolution interstitial water samples that will constrain the temperature and salinity profiles of the ocean during the Last Glacial Maximum. The expedition made major strides toward fulfilling each of these objectives. The recovered sequences allowed generation of complete spliced stratigraphic sections that span from 0 to between ~0.13 and 7 Ma. This sediment will provide decadal- to millennial-scale climatic records that will allow answering the paleoceanographic and paleoclimatic questions set out in the drilling proposal.« less

The Agulhas Current is the strongest western boundary current in the Southern Hemisphere, transporting some 70 Sv of warm and saline surface waters from the tropical Indian Ocean along the East African margin to the tip of Africa. Exchanges of heat and moisture with the atmosphere influence southern African climates, including individual weather systems such as extratropical cyclone formation in the region and rainfall patterns. Recent ocean models and paleoceanographic data further point at a potential role of the Agulhas Current in controlling the strength and mode of the Atlantic Meridional Overturning Circulation (AMOC) during the Late Pleistocene. Spillage of saline Agulhas water into the South Atlantic stimulates buoyancy anomalies that act as a control mechanism on the basin-wide AMOC, with implications for convective activity in the North Atlantic and Northern Hemisphere climate. International Ocean Discovery Program (IODP) Expedition 361 aims to extend this work to periods of major ocean and climate restructuring during the Pliocene/Pleistocene to assess the role that the Agulhas Current and ensuing (interocean) marine heat and salt transports have played in shaping the regional- and global-scale ocean and climate development. This expedition will core six sites on the southeast African margin and Indian–Atlantic ocean gateway. Themore »primary sites are located between 416 and 3040 m water depths. The specific scientific objectives are • To assess the sensitivity of the Agulhas Current to changing climates of the Pliocene/Pleistocene, in association with transient to long-term changes of high-latitude climates, tropical heat budgets, and the monsoon system; • To reconstruct the dynamics of the Indian–Atlantic gateway circulation during such climate changes, in association with changing wind fields and migrating ocean fronts; • To examine the connection between Agulhas leakage and ensuing buoyancy transfer and shifts of the AMOC during major ocean and climate reorganizations during at least the last 5 My; and • To address the impact of Agulhas variability on southern Africa terrestrial climates and, notably, rainfall patterns and river runoff. Additionally, Expedition 361 will complete an intensive interstitial fluids program at four of the sites aimed at constraining the temperature, salinity, and density structure of the Last Glacial Maximum (LGM) deep ocean, from the bottom of the ocean to the base of the main thermocline, to address the processes that could fill the LGM ocean and control its circulation. Expedition 361 will seek to recover ~5200 m of sediment in total. The coring strategy will include the triple advanced piston corer system along with the extended core barrel coring system where required to reach target depths. Given the significant transit time required during the expedition (15.5 days), the coring schedule is tight and will require detailed operational planning and flexibility from the scientific party. The final operations plan, including the number of sites to be cored and/or logged, is contingent upon the R/V JOIDES Resolution operations schedule, operational risks, and the outcome of requests for territorial permission to occupy particular sites. All relevant IODP sampling and data policies will be adhered to during the expedition. Beyond the interstitial fluids program, shipboard sampling will be restricted to acquiring ephemeral data and to limited low-resolution sampling of parameters that may be critically affected by short-term core storage. Most sampling will be deferred to a postcruise sampling party that will take place at the Gulf Coast Repository in College Station, Texas (USA). A substantial onshore X-ray fluorescence scanning plan is anticipated and will be further developed in consultation with scientific participants.« less