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Ultraviolet (UV) printing of photopolymers is a widely adopted manufacturing method because of its high resolution and throughput. However, available printable photopolymers are typically thermosets, resulting in challenges in postprocessing and recycling of printed structures. Here, we present a new process called interfacial photopolymerization (IPP) which enables photopolymerization printing of linear chain polymers. In IPP, a polymer film is formed at the interface between two immiscible liquids, one containing a chain-growth monomer and the other containing a photoinitiator. We demonstrate the integration of IPP in a proof-of-concept projection system for printing of polyacrylonitrile (PAN) films and rudimentary multi-layer shapes . IPP shows in-plane and out-of-plane resolutions comparable to conventional photoprinting methods. Cohesive PAN films with number-average molecular weights greater than 15 kg mol–1 are obtained, and to our knowledge this is the first report of photopolymerization printing of PAN. A macrokinetics model of IPP is developed to elucidate the transport and reaction rates involved and evaluate how reaction parameters affect film thickness and print speed. Last, demonstration of IPP in a multilayer scheme suggests its suitabiliy for three-dimensional printing of linear-chain polymers. 

In supramolecular materials, multiple weak binding groups can act as a single collective unit when confined to a localized volume, thereby producing strong but dynamic bonds between material building blocks. This principle of multivalency provides a versatile means of controlling material assembly, as both the number and the type of supramolecular moieties become design handles to modulate the strength of intermolecular interactions. However, in materials with building blocks significantly larger than individual supramolecular moieties (e.g., polymer or nanoparticle scaffolds), the degree of multivalency is difficult to predict or control, as sufficiently large scaffolds inherently preclude separated supramolecular moieties from interacting. Because molecular models commonly used to examine supramolecular interactions are intrinsically unable to examine any trends or emergent behaviors that arise due to nanoscale scaffold geometry, our understanding of the thermodynamics of these massively multivalent systems remains limited. Here we address this challenge via the coassembly of polymer-grafted nanoparticles and multivalent polymers, systematically examining how multivalent scaffold size, shape, and spacing affect their collective thermodynamics. Investigating the interplay of polymer structure and supramolecular group stoichiometry reveals complicated but rationally describable trends that demonstrate how the supramolecular scaffold design can modulate the strength of multivalent interactions. This approach to self-assembled supramolecular materials thus allows for the manipulation of polymer−nanoparticle composites with controlled thermal stability, nanoparticle organization, and tailored meso- to microscopic structures. The sophisticated control of multivalent thermodynamics through precise modulation of the nanoscale scaffold geometry represents a significant advance in the ability to rationally design complex hierarchically structured materials via self-assembly. 

To help straddle the breadth of research on doctoral student stress, our team sought to explore the landscape of doctoral student stressors by interviewing an intentionally stratified sample of doctoral students four times during the course of an academic year. We present an overview of our research process and the top 10 most reported stressors from analysis of our interview data. Further, we report on the most frequent coping strategies used by students in our sample, contributing additional coping strategies used by engineering doctoral students. Understanding the most common factors which contribute to the stresses experienced by doctoral students and these students' effective coping strategies can support students, advisors, and departments to develop proactive interventions and strategies that support well-being and retention. 

The first simultaneous measurements of the ${\nu }_{\mu }$quasielasticlike cross section on C, CH, ${\mathrm{H}}_2\mathrm{O}$, Fe, and Pb targets as a function of kinematic imbalance variables in the plane transverse to the incoming neutrino direction are presented. These variables combine the muon and proton information to provide a new way to disentangle the effects of the nucleus in quasielasticlike processes. The data were obtained using a wideband ${\nu }_{\mu }$beam with $⟨{\mathrm{E}}_{\nu }⟩\sim 6\mathrm{GeV}$. Cross-section ratios of the different target materials to CH are also shown. These measurements are used to explore the nature of the cross-section $A$scaling, as well as initial and final state interaction effects. Comparisons are made to predictions from a number of commonly used neutrino Monte Carlo event generators. The range of predictions of the different models tends to cover the data but the degree and consistency of the agreement suffers in regions, and on higher $A$targets, where the final state interactions are expected to be more pronounced.