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Bheemireddy, Sambasiva R. ; Hussain, Waseem A. ; Uddin, Ain ; Du, Yachu ; Hautzinger, Matthew P. ; Kevorkian, Paul V. ; Petrie, Frankie A. ; Plunkett, Kyle N. ( , Chemical Communications)Isomerically pure 5,11-dibromo-2,8-dihexylanthra[2,3- b :76- b ′]dithiophene, a brominated analog of anthracenedithiophene (ADT), was prepared and utilized for a palladium catalyzed cyclopentannulation reaction with 3,3′-dimethoxy-phenylacetylene to give cyclopentannulated ADT (CP-ADTs). A further Scholl cyclodehydrogenation reaction gave contorted aromatics with large splay angles, low optical gaps, and low LUMOs.more » « less
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Hautzinger, Matthew P. ; Raulerson, Emily K. ; Harvey, Steven P. ; Liu, Tuo ; Duke, Daniel ; Qin, Xixi ; Scheidt, Rebecca A. ; Wieliczka, Brian M. ; Phillips, Alan J. ; Graham, Kenneth R. ; et al ( , Journal of the American Chemical Society)
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Chen, Jie ; Morrow, Darien J. ; Fu, Yongping ; Zheng, Weihao ; Zhao, Yuzhou ; Dang, Lianna ; Stolt, Matthew J. ; Kohler, Daniel D. ; Wang, Xiaoxia ; Czech, Kyle J. ; et al ( , Journal of the American Chemical Society)