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Abstract Polymer membranes with ultrahigh CO₂permeabilities and high selectivities are needed to address some of the critical separation challenges related to energy and the environment, especially in natural gas purification and postcombustion carbon capture. However, very few solution‐processable, linear polymers are known today that access these types of characteristics, and all of the known structures achieve their separation performance through the design of rigid backbone chemistries that concomitantly increase chain stiffness and interchain spacing, thereby resulting in ultramicroporosity in solid‐state chain‐entangled films. Herein, the separation performance of a porous polymer obtained via ring‐opening metathesis polymerization is reported, which possesses a flexible backbone with rigid, fluorinated side chains. This polymer exhibits ultrahigh CO₂permeability (>21 000 Barrer) and exceptional plasticization resistance (CO₂plasticization pressure > 51 bar). Compared to traditional polymers of intrinsic microporosity, the rate of physical aging is slower, especially for gases with small effective diameters (i.e., He, H₂, and O₂). This structural design strategy, coupled with studies on fluorination, demonstrates a generalizable approach to create new polymers with flexible backbones and pore‐forming side chains that have unexplored promise for small‐molecule separations. 

ABSTRACT The All-Sky Automated Survey for Supernovae (ASAS-SN) provides long baseline (∼4 yr) light curves for sources brighter than V ≲ 17 mag across the whole sky. As part of our effort to characterize the variability of all the stellar sources visible in ASAS-SN, we have produced ∼30.1 million V-band light curves for sources in the Southern hemisphere using the APASS DR9 (AAVSO Photometric All-Sky Survey Data Release) catalogue as our input source list. We have systematically searched these sources for variability using a pipeline based on random forest classifiers. We have identified $${\sim } 220\, 000$$ variables, including $${\sim } 88\, 300$$ new discoveries. In particular, we have discovered $${\sim }48\, 000$$ red pulsating variables, $${\sim }23\, 000$$ eclipsing binaries, ∼2200 δ-Scuti variables, and $${\sim }10\, 200$$ rotational variables. The light curves and characteristics of the variables are all available through the ASAS-SN variable stars data base (https://asas-sn.osu.edu/variables). The pre-computed ASAS-SN V-band light curves for all the ∼30.1 million sources are available through the ASAS-SN photometry data base (https://asas-sn.osu.edu/photometry). This effort will be extended to provide ASAS-SN light curves for sources in the Northern hemisphere and for V ≲ 17 mag sources across the whole sky that are not included in APASS DR9.