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It is clear from modern analogue studies that O2-deficient conditions favor preservation of organic matter (OM) in fine-grained sedimentary rocks (black shales). It is also clear that appreciable productivity and OM flux to the sediment are required to establish and maintain these conditions. However, debates regarding redox controls on OM accumulation in black shales have mainly focused on oxic versus anoxic conditions, and the implications of different anoxic redox states remain unexplored. Here, we present detailed multi-proxy sedimentary geochemical studies of major Paleozoic and Mesozoic North American black shale units to elucidate their depositional redox conditions. This is the first broad-scale study to use a consistent geochemical methodology and to incorporate data from Fe-speciation – presently the only redox proxy able to clearly distinguish anoxic depositional conditions as ferruginous (H2S-limited) or euxinic (H2S-replete, Fe-limited). These data are coupled with total organic carbon (TOC), programmed pyrolysis, and redox-sensitive trace element proxies, with almost all measurements analyzed using the same geochemical methodology. Consistent with expectations based on previous geochemical and paleontological/ichnological studies, these analyses demonstrate that the study units were almost exclusively deposited under anoxic bottom waters. These analyses also demonstrate that there is wide variance in the prevalence of euxinic versus ferruginous conditions, with many North American black shale units deposited under predominantly ferruginous or oscillatory conditions. TOC is significantly higher under euxinic bottom waters in analyses of both preserved (present day) TOC and reconstructed initial TOC values, although sediments deposited under both redox states do have economically viable TOC content. While this correlation does not reveal the mechanism behind higher organic enrichment in euxinic environments, which may be different in different basins, it does open new research avenues regarding resource exploration and the biogeochemistry of ancient reducing environments. 

Abstract. The upper Paleozoic Cutler Group of southern Utah, USA, is a key sedimentary archive for understanding the Earth-life effects of the planet's last pre-Quaternary icehouse–hothouse state change: the Carboniferous–Permian (C–P) transition, between 304 and 290 million years ago. Within the near-paleoequatorial Cutler Group, this transition corresponds to a large-scale aridification trend, loss of aquatic habitats, and ecological shifts toward more terrestrial biota as recorded by its fossil assemblages. However, fundamental questions persist. (1) Did continental drift or shorter-term changes in glacio-eustasy, potentially driven by orbital (Milankovitch) cycles, influence environmental change at near-equatorial latitudes during the C–P climatic transition? (2) What influence did the C–P climatic transition have on the evolution of terrestrial ecosystems and on the diversity and trophic structures of terrestrial vertebrate communities? The Paleozoic Equatorial Records of Melting Ice Ages (PERMIA) project seeks to resolve these issues in part by studying the Elk Ridge no. 1 (ER-1) core, complemented by outcrop studies. This legacy core, collected in 1981 within what is now Bears Ears National Monument, recovered a significant portion of the Hermosa Group and the overlying lower Cutler Group, making it an ideal archive for studying paleoenvironmental change during the C–P transition. As part of this project, the uppermost ∼ 450 m of the core were temporarily transferred from the Austin Core Repository Center to the Continental Scientific Drilling Facility at the University of Minnesota for splitting, imaging, and scanning for geophysical properties and spectrophotometry. Here we (1) review the history of this legacy core, (2) introduce recently obtained geophysical and lithologic datasets based on newly split and imaged core segments to provide a sedimentological and stratigraphic overview of the Elk Ridge no. 1 core that aligns more accurately with the currently recognized regional lithostratigraphic framework, (3) establish the position of the boundary between the lower Cutler beds and the overlying Cedar Mesa Sandstone in the core, and (4) outline our ongoing research goals for the core. In-progress work on the core aims to refine biostratigraphic and chemostratigraphic age constraints, retrieve the polarity stratigraphy, interrogate preserved cyclostratigraphy, analyze sedimentary structures and paleosol facies, investigate stable isotope geochemistry, and evaluate elemental abundance data from X-ray fluorescence (XRF) scanning. Together with outcrop studies throughout Bears Ears National Monument and its vicinity, these cores will allow the rich paleontological and paleoenvironmental archives recorded in the continental Carboniferous–Permian transition of western North America to be confidently placed in a robust chronologic context that will help test hypotheses relating ecosystem evolution to the Carboniferous rainforest collapse, initial decline of the Late Paleozoic Ice Age, and long-wavelength astronomical cycles pacing global environmental change. 

Abstract The Permian marine-terrestrial system of the North China block provides an exceptional window into the evolution of northern temperate ecosystems during the critical transition from icehouse to greenhouse following the late Paleozoic ice age (LPIA). Despite many studies on its rich hydrocarbon reserves and climate-sensitive fossil flora, uncertain temporal constraints and correlations have hampered a thorough understanding of the records of geologic, biologic, and climatic change from the North China block. We present a new chronostratigraphy based on high-precision U-Pb chemical abrasion–isotope dilution–thermal ionization mass spectrometry (CA-ID-TIMS) geochronology of tuffs from a near-complete latest Carboniferous–Permian succession in North China. The results indicate that the predominance of continental red beds, climate aridification, and the disappearance of coals and characteristic tropical flora were well under way during the Cisuralian (Early Permian) in the North China block, significantly earlier than previously thought. A nearly 20 m.y. hiatus spanning the early Kungurian to the mid-Guadalupian (or later) is revealed in the northern North China block to have close temporal and spatial associations with the closure and/or subduction of the Paleo-Asian Ocean and its related tectonic convergence. This long hiatus was concomitant with the prominent loss of the highly diverse and abundant Cathaysian floras and the widespread invasion of the monotonous Angaran floras under arid climate conditions in the North China block. Similarities in the floral and climate shift histories between Euramerica and North China suggest that aside from the regional tectonic controls and continental movement, extensive volcanism during the Cisuralian may have played a major role in the global warming and aridification in the aftermath of the LPIA.