An experimental study of the configurational thermodynamics for a series of near-eutectic Pt80-
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x Cux P20bulk metallic glass-forming alloys is reported where 14 <x < 27. The undercooled liquid alloys exhibit very high fragility that increases asx decreases, resulting in an increasingly sharp glass transition. With decreasingx , the extrapolated Kauzmann temperature of the liquid,T K , becomes indistinguishable from the conventionally defined glass transition temperature,T g . Forx < 17, the observed liquid configurational enthalpy vs.T displays a marked discontinuous drop or latent heat at a well-defined freezing temperature,T gm . The entropy drop for this first-order liquid/glass transition is approximately two-thirds of the entropy of fusion of the crystallized eutectic alloy. BelowT gm ,more »