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Nanoporous carbons play an important role in different electrochemical applications such as being utilized as electrodes in supercapacitors. Application of electric potential to a porous electrode in electrolyte solution stimulates adsorption or desorption of ions on the electrode surface. Electrosorption causes appearance of solvation pressure in the pores and results in electrode deformation. In this work, using molecular dynamics simulations and the continuum theory based on the modified Poisson-Boltzmann equation, we studied the structure of the electrical double layer in slit graphitic micropores filled with a NaCl aqueous solution, and solvation pressure in these pores. We focused on the behavior of the solvation pressure as a function of pore width and surface charge density. Within molecular dynamics simulations, two different water models were used -- an explicit model based on SPC/E water molecules and an implicit model, i.e., structureless background with fixed dielectric permittivity. The latter allows us to relate molecular dynamics simulations to the continuum theory. Simulations with explicit water show a qualitatively different behavior of the solvation pressure in the 1 and 2 nm pores as a function of the surface charge density. We demonstrated that the value of the solvation pressure is defined by a delicate balance between Van der Waals and electrostatic contributions. We demonstrated that the theory predicts the dependence of the solvation pressure on the pore width, which matches the results of simulations using the implicit water model. Finally, we adapted the continuum theory, developed for adsorption-induced deformation to estimate the deformation of a carbon electrode due to electrosorption. Our results can be used in the further development of nanoporous actuators working based on electrosorption-induced deformation. 

Abstract Sterile neutrinos can be produced through mixing with active neutrinos in the hot, dense core of a core-collapse supernova (SN). The standard bounds on the active-sterile mixing (sin²θ) from SN arise from SN1987A energy-loss, requiringE_loss< 10⁵²erg. In this work, we discuss a novel bound on sterile neutrino parameter space arising from the energy deposition through its decays inside the SN envelope. Using the observed underluminous SN IIP population, this energy deposition is constrained to be below ∼ 10⁵⁰erg. Focusing on sterile neutrino mixing only with tau neutrino, for heavy sterile massesm_sin the range 100 – 500 MeV, we find stringent constraints on sin²θ_τreaching two orders of magnitude lower than those from the SN1987A energy loss argument, thereby probing the mixing angles required for Type-I seesaw mechanism. Similar bounds will also be applicable to sterile mixing only with muons (sin²θ_μ). 

Beyond the Standard Model electromagnetic properties of neutrinos may lead to copious production of sterile neutrinos in the hot and dense core of a core-collapse supernova. In this work, we focus on the active-sterile transition magnetic moment portal for heavy sterile neutrinos. Firstly, we revisit the SN1987A cooling bounds for dipole portal using the integrated luminosity method, which yields more reliable results (especially in the trapping regime) compared to the previously explored via emissivity loss, also known as the Raffelt criterion. Secondly, we obtain strong bounds on the dipole coupling strength reaching as low as 10^{-11} /GeV from energy deposition, i.e., constrained from the observation of explosion energies of underluminous Type IIP supernovae. In addition, we find that sterile neutrino production from Primakoff upscattering off of a proton dominates over scattering off of an electron for low sterile neutrino masses. 

Systematic land use planning to address environmental impacts does not typically include human health and wellbeing as explicit inputs. We tested the effects of including issues related to human health, ecosystem services, and community wellbeing on the outputs of a standard land use planning process which is primarily focused on environmental variables. We consulted regional stakeholders to identify the health issues that have environmental links in the Sacramento, California region and to identify potential indicators and datasets that can be used to assess and track these issues. Marxan planning software was used to identify efficient land use patterns to maximize both ecological conservation and human health outcomes. Outputs from five planning scenarios were compared and contrasted, resulting in a spatially explicit series of tradeoffs across the scenarios. Total area required to meet imputed goals ranged from 10.4% to 13.4% of the total region, showing somewhat less efficiency in meeting biodiversity goals when health outcomes are included. Additionally, we found 4.8% of residential areas had high greening needs, but this varied significantly across the six counties. The work provides an example of how integrative assessment can help inform management decisions or stakeholder negotiations potentially leading to better management of the production landscapes in food systems. 

Solving the wicked problems of food system sustainability requires a process of knowledge co-production among diverse actors in society. We illustrate a generalized workflow for knowledge co-production in food systems with a pair of case studies from the response of the meat and dairy production sectors in the wake of the COVID-19 pandemic. The first case study serves as an example of a scientific workflow and uses a GIS method (location allocation) to examine the supply chain linkages between meat and dairy producers and processors in Ohio. This analysis found that meat producers and processors are less clustered and more evenly distributed across the state than dairy producers and processors, with some dairy processors potentially needing to rely on supply from producers up to 252 km away. The second case study in California adds an example of a stakeholder workflow in parallel to a scientific workflow and describes the outcome of a series of interviews with small and mid-scale meat producers and processors concerning their challenges and opportunities, with the concentration of processors arising as the top challenge faced by producers. We present a pair of workflow diagrams for the two case studies that illustrate where the processes of knowledge co-production are situated. Examining these workflow processes highlights the importance of data privacy, data governance, and boundary spanners that connect stakeholders.