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Carbonate minerals contain stable isotopes of carbon and oxygen with different masses whose abundances and bond arrangement are governed by thermodynamics. The clumped isotopic value Δ_iis a measure of the temperature-dependent preference of heavy C and O isotopes to clump, or bond with or near each other, rather than with light isotopes in the carbonate phase. Carbonate clumped isotope thermometry uses Δ_ivalues measured by mass spectrometry (Δ₄₇, Δ₄₈) or laser spectroscopy (Δ₆₃₈) to reconstruct mineral growth temperature in surface and subsurface environments independent of parent water isotopic composition. Two decades of analytical and theoretical development have produced a mature temperature proxy that can estimate carbonate formation temperatures from 0.5 to 1,100°C, with up to 1–2°C external precision (2 standard error of the mean). Alteration of primary environmental temperatures by fluid-mediated and solid-state reactions and/or Δ_ivalues that reflect nonequilibrium isotopic fractionations reveal diagenetic history and/or mineralization processes. Carbonate clumped isotope thermometry has contributed significantly to geological and biological sciences, and it is poised to advance understanding of Earth's climate system, crustal processes, and growth environments of carbonate minerals. ▪ Clumped heavy isotopes in carbonate minerals record robust temperatures and fluid compositions of ancient Earth surface and subsurface environments. ▪ Mature analytical methods enable carbonate clumped Δ₄₇, Δ₄₈, and Δ₆₃₈measurements to address diverse questions in geological and biological sciences. ▪ These methods are poised to advance marine and terrestrial paleoenvironment and paleoclimate, tectonics, deformation, hydrothermal, and mineralization studies. 

Abstract Profound effects of episodic megafloods (≥10⁶ m³/s) have been observed on Earth and Mars. Quaternary megafloods sourced from valley‐blocking glaciers on the Tibetan Plateau likely play an important role in the geomorphic evolution of the Yarlung‐Tsangpo Gorge and mountain landscape of the eastern Himalaya. We use the first 2D numerical simulation of a megaflood sourced from a reconstructed 81 km³Tibetan lake to analyze flood hydraulics and examine the erosional and depositional potential of megafloods in mountain landscapes. The simulated flood has a duration >60 hr and a peak discharge of 3.1 × 10⁶ m³/s. We find that the extent of inundated features like terraces, narrow valley sections, tight meander bends, and overtopped ridges influences locations of observed maximum depth (370 m), speed (76 m/s), and bed shear stress (>100 kPa), creating dynamic patterns of erosive potential. Consequently, it is difficult to predict local (≤1 km) patterns of megaflood erosional potential from either unit stream power or flood power from smaller magnitude outburst floods. However, both are useful when predicting regional (≥25 km) order‐of‐magnitude shifts in megaflood flood power. Portions of the flood domain downstream of the Gorge experience lower bed shear stresses and flood power <5 kW/m², indicating potential for significant deposition. We suggest widespread deposition of boulders within the modern channel and fine‐grained particles on hillslopes during a megaflood likely impedes subsequent erosion and affects channel width and longitudinal form throughout the flood pathway. Our findings show the legacy of megaflooding in mountainous terrain includes both extensive erosion and deposition.