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  1. The effects of dispersion on migratory insertion reactions and related iron–carbon bond dissociation energies pertaining to (Me 2 IPr)FeR 2 (R = neo Pe, 1-nor), and the conversion of (Me 2 IPr)Fe(NAd)R 2 to (Me 2 IPr)Fe{N(Ad}R)R are investigated via calculations and structural comparisons. Dispersion appears to be an underappreciated, major contributor to common structure and reactivity relationships. 
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