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Creators/Authors contains: "Jankins, Tanner C"

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  1. ; ; ; ; (, Chemical Science)
    A stereodivergent, W-catalyzed alkene isomerization is reported, leading to eitherE- orZ-β,γ-unsaturated carbonyl compounds based on the ligand environment around the metal. 
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    Free, publicly-accessible full text available January 29, 2026
  2. ; ; ; ; ; ; ; ; ; (, Organometallics)
    Full Text Available 
  3. ; ; ; ; ; ; ; (, Angewandte Chemie International Edition)
    Abstract A nickel‐catalyzed conjunctive cross‐coupling of alkenyl carboxylic acids, aryl iodides, and aryl/alkenyl boronic esters is reported. The reaction delivers the desired 1,2‐diarylated and 1,2‐arylalkenylated products with excellent regiocontrol. To demonstrate the synthetic utility of the method, a representative product is prepared on gram scale and then diversified to eight 1,2,3‐trifunctionalized building blocks using two‐electron and one‐electron logic. Using this method, three routes toward bioactive molecules are improved in terms of yield and/or step count. This method represents the first example of catalytic 1,2‐diarylation of an alkene directed by a native carboxylate group. 
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