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Goodkin, Nathalie (Ed.)Abstract Most oceanic lead (Pb) is from anthropogenic emissions into the atmosphere deposited into surface waters, mostly during the past two centuries. The space‐ and time‐dependent emission patterns of anthropogenic Pb (and its isotope ratios) constitute a global geochemical experiment providing information on advective, mixing, chemical, and particle flux processes redistributing Pb within the ocean. Pb shares aspects of its behavior with other elements, for example, atmospheric input, dust solubilization, biological uptake, and reversible exchange between dissolved and adsorbed Pb on sinking particles. The evolving distributions allow us to see signals hidden in steady‐state tracer distributions. The global anthropogenic Pb emission experiment serves as a tool to understand oceanic trace element dynamics. We obtained a high‐resolution (5° station spacing) depth transect of dissolved Pb concentrations and Pb isotopes from Alaska (55°N) to just north of Tahiti (20°S) near 152°W longitude. The sections reveal distinct sources of Pb (American, Australian, and Chinese), transport of Australian style Pb to the water mass formation region of Sub‐Antarctic Mode Water which is advected northward, columnar Pb isotope contours due to reversible particle exchange on sinking particles from high‐productivity particle veils, and a gradient of high northern deep water [Pb] to low southern deep water [Pb] that is created by reversible exchange release of Pb from sinking particles carrying predominantly northern hemisphere Pb.208Pb/206Pb versus206Pb/207Pb isotope relationships show that most oceanic Pb in the North Pacific is from Chinese and American sources, whereas Pb in the South Pacific is from Australian and American sources.more » « lessFree, publicly-accessible full text available January 1, 2026
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Reversible scavenging, the oceanographic process by which dissolved metals exchange onto and off sinking particles and are thereby transported to deeper depths, has been well established for the metal thorium for decades. Reversible scavenging both deepens the elemental distribution of adsorptive elements and shortens their oceanic residence times in the ocean compared to nonadsorptive metals, and scavenging ultimately removes elements from the ocean via sedimentation. Thus, it is important to understand which metals undergo reversible scavenging and under what conditions. Recently, reversible scavenging has been invoked in global biogeochemical models of a range of metals including lead, iron, copper, and zinc to fit modeled data to observations of oceanic dissolved metal distributions. Nonetheless, the effects of reversible scavenging remain difficult to visualize in ocean sections of dissolved metals and to distinguish from other processes such as biological regeneration. Here, we show that particle-rich “veils” descending from high-productivity zones in the equatorial and North Pacific provide idealized illustrations of reversible scavenging of dissolved lead (Pb). A meridional section of dissolved Pb isotope ratios across the central Pacific shows that where particle concentrations are sufficiently high, such as within particle veils, vertical transport of anthropogenic surface–dissolved Pb isotope ratios toward the deep ocean is manifested as columnar isotope anomalies. Modeling of this effect shows that reversible scavenging within particle-rich waters allows anthropogenic Pb isotope ratios from the surface to penetrate ancient deep waters on timescales sufficiently rapid to overcome horizontal mixing of deep water Pb isotope ratios along abyssal isopycnals.more » « less
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