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Creators/Authors contains: "Kallingal, Isha A"

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  1. ; ; ; (, Acta Crystallographica Section E Crystallographic Communications)
    Aμ-oxo vanadium(V) dimeric complex, μ-oxido-bis[(2,2′-{[ethane-1,2-diylbis(azanediyl)]bis(methylene)}diphenolato)oxidovanadium(V)], [V2(C16H18N2O2)2O3] (1), was crystallized by slow evaporation from an ethanol solution. Theμ-oxo dimer crystallizes in the monoclinic space groupC2/cwhere the salan ligand1acoordinates to the vanadium center in a κ2N,κ2Ofashion, forming a distorted octahedral geometry. The bridging oxo ligand lies on a crystallographic twofold axis. The unit cell consists of four molecules of1that are linked by C—H...·πareneinteractions as well as intramolecular hydrogen bonding. 
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    Free, publicly-accessible full text available November 1, 2026