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Barrios-Vargas, Luz Jimena; Abeynayake, Niroshani Samitri; Secrist, Carlee; Le, Nghia; Webster, Charles Edwin; Donnadieu, Bruno; Kaphan, David M; Roy, Amitava; Ibarra, Ilich A.; Montiel-Palma, Virginia (, Dalton Transactions)MOF NU-1000 was employed to host Ni tripodal complexes prepared from new organometallic precursors [HNi(κ4(E,P,P,P)-E(o-C 6 H 4 CH 2 PPh 2 ) 3 ], E = Si (Ni-1), Ge (Ni-2). The new heterogenous catalytic materials, Ni-1@NU-1000 and Ni-2@NU-1000 show the advantages of both homogenous and heterogeneous catalysts. They catalyze the hydroboration of aldehydes and ketones more efficiently than the homogenous Ni-1 and Ni-2, under aerobic conditions, and allowing recyclability of the catalyst.more » « less
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Patel, Prajay; Wells, Robert H.; Kaphan, David M.; Delferro, Massimiliano; Skodje, Rex T.; Liu, Cong (, ACS Catalysis)null (Ed.)
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Witzke, Ryan J.; Chapovetsky, Alon; Conley, Matthew P.; Kaphan, David M.; Delferro, Massimiliano (, ACS Catalysis)null (Ed.)