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While many previous studies have indicated that encouraging a growth mindset can improve student learning outcomes, this conclusion’s applicability to college-level astronomy classrooms remains poorly understood owing to the variation in students’ overall and domain-specific learning attitudes. To address this, we surveyed undergraduate students in an introductory astronomy class about their attitudes towards learning astronomy over the course of five semesters. Overall, students felt an affinity for astronomy, felt moderately competent, perceived astronomy to be intermediate in terms of difficulty, and agreed strongly with standard statements reflecting a “growth mindset,” i.e., the belief that intelligence is malleable rather than fixed from birth. Their responses were stable over the course of the semester and did not appear to depend strongly on student demographics. The unexpected start of the COVID-19 pandemic and the associated shift to all-virtual learning correlated with a drop in their affinity for astronomy, a small decrease in their perceived competence, and an increase in the perceived difficulty of the topic. Their overall learning mindset showed negligible change during this time, emphasizing the stability of their belief in a growth mindset as compared to other measured learning attitudes. However, more nuanced questions about their behaviors and interpretations in the classroom, about how they felt “in the moment,” and about what factors were most important for their success in the class revealed significantly lower alignment with a growth mindset. This suggests that while introductory astronomy students may believe that they have a growth mindset, this mindset is not necessarily reflected in their self-reported classroom behaviors or measured responses to actual learning challenges. Published by the American Physical Society2024 

This dataset archived with the Earthref Magnetics Information Consortium contains low-temperature remanent magnetization data generated at the Institute for Rock Magnetism, University of Minnesota. This dataset accompanies the publication McCartney, K., Hammer, J.E., Shea, T., Brachfeld, S., Giachetti, T., 2024. Investigating the role of nanoscale titanomagnetite in bubble nucleation via novel applications of magnetic analyses (Dataset), Magnetics Information Consortium (MagIC), doi:10.7288/V4/MAGIC/20019. 

This dataset archived with the Magnetics Information Consortium contains rock-magnetic data for rhyolitic pumice and obsidian from Glass Mountain, Medicine Lake, California, USA. Data were generated at Montclair State University and include magnetic susceptibility measured at 976Hz and 3904Hz, magnetic susceptibility vs. temperature, anhysteretic remanent magnetization (ARM), and magnetic hysteresis measurements. This dataset accompanies the publication Brachfeld, S., McCartney, K., Hammer, J.E., Shea, T., Giachetti, T., Evaluating the role of titanomagnetite in bubble nucleation: Rock magnetic detection and characterization of nanolites and ultra-nanolites in rhyolite pumice and obsidian from Glass Mountain, California, Geochemistry Geophysics Geosystems, https://doi.org/10.1029/2023GC011336. 

We document the presence, composition, and number density (TND) of titanomagnetite nanolites and ultra‐nanolites in aphyric rhyolitic pumice, obsidian, and vesicular obsidian from the 1060 CE Glass Mountain volcanic eruption of Medicine Lake Volcano, California, using magnetic methods. Curie temperatures indicate compositions of Fe2.40Ti0.60O4 to Fe3O4. Rock‐magnetic parameters sensitive to domain state, which is dependent on grain volume, indicate a range of particle sizes spanning superparamagnetic (<50–80 nm) to multidomain (>10 μm) particles. Cylindrical cores drilled from the centers of individual pumice clasts display anisotropy of magnetic susceptibility with prolate fabrics, with the highest degree of anisotropy coinciding with the highest vesicularity. Fabrics within a pumice clast require particle alignment within a fluid, and are interpreted to result from the upward transport of magma driven by vesiculation, ensuing bubble growth, and shearing in the conduit. Titanomagnetite number density (TND) is calculated from titanomagnetite volume fraction, which is determined from ferromagnetic susceptibility. TND estimates for monospecific assemblages of 1,000 nm–10 nm cubes predict 10^12 to 10^20 m^−3 of solid material, respectively. TND estimates derived using a power law distribution of grain sizes predict 10^18 to 10^19  m^−3. These ranges agree well with TND determinations of 10^18 to 10^20  m^−3 made by McCartney et al. (2024), and are several orders of magnitude larger than the number density of bubbles in these materials. These observations are consistent with the hypothesis that titanomagnetite crystals already existed in extremely high number‐abundance at the time of magma ascent and bubble nucleation. 

Nucleation of H2O vapor bubbles in magma requires surpassing a chemical supersaturation threshold via decompression. The threshold is minimized in the presence of a nucleation substrate (heterogeneous nucleation, <50 MPa), and maximized when no nucleation substrate is present (homogeneous nucleation, >100 MPa). The existence of explosively erupted aphyric rhyolite magma staged from shallow (<100 MPa) depths represents an apparent paradox that hints at the presence of a cryptic nucleation substrate. In a pair of studies focusing on Glass Mountain eruptive units from Medicine Lake, California, we characterize titanomagnetite nanolites and ultrananolites in pumice, obsidian, and vesicular obsidian (Brachfeld et al., 2024,https://doi.org/10.1029/2023GC011336), calculate titanomagnetite crystal number densities, and compare titanomagnetite abundance with the physical properties of pumice to evaluate hypotheses on the timing of titanomagnetite crystallization. Titanomagnetite crystals with grain sizes of approximately 3–33 nm are identified in pumice samples from the thermal unblocking of low‐temperature thermoremanent magnetization. The titanomagnetite number densities for pumice are 10^18 to 10^20 m^−3, comparable to number densities in pumice and obsidian obtained from room temperature methods (Brachfeld et al., 2024,https://doi.org/10.1029/2023GC011336'>https://doi.org/10.1029/2023GC011336). This range exceeds reported bubble number densities (BND) within the pumice from the same eruptive units (average BND ∼4 × 10^14 m^−3). The similar abundances of nm‐scale titanomagnetite crystals in the effusive and explosive products of the same eruption, together with the lack of correlation between pumice permeability and titanomagnetite content, are consistent with titanomagnetite formation having preceded the bubble formation. Results suggest sub‐micron titanomagnetite crystals are responsible for heterogeneous bubble nucleation in this nominally aphyric rhyolite magma. 

It has long been known that the alteration of protein side chains that occlude or expose the heme cofactor to water can greatly affect the stability of the oxyferrous heme state. Here, we demonstrate that the rate of dynamically driven water penetration into the core of an artificial oxygen transport protein also correlates with oxyferrous state lifetime by reducing global dynamics, without altering the structure of the active site, via the simple linking of the two monomers in a homodimeric artificial oxygen transport protein using a glycine-rich loop. The tethering of these two helices does not significantly affect the active site structure, pentacoordinate heme-binding affinity, reduction potential, or gaseous ligand affinity. It does, however, significantly reduce the hydration of the protein core, as demonstrated by resonance Raman spectroscopy, backbone amide hydrogen exchange, and pKa shifts in buried histidine side chains. This further destabilizes the charge-buried entatic state and nearly triples the oxyferrous state lifetime. These data are the first direct evidence that dynamically driven water penetration is a rate-limiting step in the oxidation of these complexes. It furthermore demonstrates that structural rigidity that limits water penetration is a critical design feature in metalloenzyme construction and provides an explanation for both the failures and successes of earlier attempts to create oxygen-binding proteins. 

Abstract Recent wide-field integral-field spectroscopy has revealed the detailed properties of high-redshift Lyαnebulae, most often targeted due to the presence of an active galactic nucleus (AGN). Here, we use VLT/MUSE to resolve the morphology and kinematics of a nebula initially identified due to strong Lyαemission atz∼ 3.2 (LABn06). Our observations reveal a two-lobed Lyαnebula, at least ∼173 pkpc in diameter, with a light-weighted centroid near a mid-infrared source (within ≈17.2 pkpc) that appears to host an obscured AGN. The Lyαemission near the AGN is also coincident in velocity with the kinematic center of the nebula, suggesting that the nebula is both morphologically and kinematically centered on the AGN. Compared to AGN-selected Lyαnebulae, the surface-brightness profile of this nebula follows a typical exponential profile at large radii (>25 pkpc), although at small radii, the profile shows an unusual dip at the location of the AGN. The kinematics and asymmetry are similar to, and the Civand Heiiupper limits are consistent with, other AGN-powered Lyαnebulae. Double-peaked and asymmetric line profiles suggest that Lyαresonant scattering may be important in this nebula. These results support the picture of the AGN being responsible for powering a Lyαnebula that is oriented roughly in the plane of the sky. Further observations will explore whether the central surface-brightness depression is indicative of either an unusual gas or dust distribution or variation in the ionizing output of the AGN over time.