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Abstract While salinity can alter the photodegradation of hydrophobic organic compounds (HOCs), the cause of their altered kinetics in seawater is not well understood. Because HOC intermediate photoproducts are often more toxic than their parent compounds, characterizing the generation of intermediates in saline environments is needed to accurately predict their health effects. The present study investigated the influence of salinity on the generation of anthraquinone through the photolysis of anthracene and the generation of anthrone and 1-hydroxyanthraquinone from the photolysis of anthraquinone as well as their reactivities with hydroxyl radicals. This was conducted by measuring the photolysis rates of anthracene and anthraquinone and characterizing their product formation in buffered deionized water, artificial seawater, individual seawater halides (bromide, chloride, and iodide), dimethyl sulfoxide, furfuryl alcohol, and solutions of hydrogen peroxide. Salinity enhanced the persistence of anthraquinone by a factor >10 and altered its product formation, including the generation of the suspected carcinogen 1-hydroxyanthraquinone. In part, this was attributed to reactive oxygen species (ROS) scavenging by the seawater constituents chloride and bromide. In addition, anthraquinone and its hydroxylated products were found to be moderately to highly reactive with hydroxyl radicals, further illustrating their tendency to react with ROS in aqueous environments. The present study emphasizes the importance of considering the effects of salinity on organic contaminant degradation; it can significantly enhance the persistence of HOCs and alter their intermediate formation, subsequently impacting chemical exposure times and potential toxic effects on estuarine/marine organisms. Environ Toxicol Chem 2023;42:1721–1729. © 2023 SETAC. 

Abstract This study reconstructs total electron content (TEC) maps in the vicinity of the Korean Peninsula by employing a deep convolutional generative adversarial network and Poisson blending (DCGAN‐PB). Our interest is to rebuild small‐scale ionosphere structures on the TEC map in a local region where pronounced ionospheric structures, such as the equatorial ionization anomaly, are absent. The reconstructed regional TEC maps have a domain of 120°–135.5°E longitude and 25.5°–41°N latitude with 0.5° resolution. To achieve this, we first train a DCGAN model by using the International Reference Ionosphere‐based TEC maps from 2002 to 2019 (except for 2010 and 2014) as a training data set. Next, the trained DCGAN model generates synthetic complete TEC maps from observation‐based incomplete TEC maps. Final TEC maps are produced by blending of synthetic TEC maps with observed TEC data by PB. The performance of the DCGAN‐PB model is evaluated by testing the regeneration of the masked TEC observations in 2010 (solar minimum) and 2014 (solar maximum). Our results show that a good correlation between the masked and model‐generated TEC values is maintained even with a large percentage (∼80%) of masking. The performance of the DCGAN‐PB model is not sensitive to local time, solar activity, and magnetic activity. Thus, the DCGAN‐PB model can reconstruct fine ionospheric structures in regions where observations are sparse and distinguishing ionospheric structures are absent. This model can contribute to near real‐time monitoring of the ionosphere by immediately providing complete TEC maps.