Search for: All records

Cross-link heterogeneity and topological defects have been shown to affect the moduli of polymer networks in the low-strain regime. Probing their role in the high-strain regime, however, has been difficult because of premature network fracture. Here, we address this problem by using a double-network approach to investigate the high-strain behavior of both randomly and regularly cross-linked networks with the same backbone chemistry. Randomly cross-linked poly(n-butyl acrylate) networks with target molecular weights between cross-links of 5–30 kg/mol were synthesized via free-radical polymerization, while regularly cross-linked poly(n-butyl acrylate) networks with molecular weights between cross-links of 7–38 kg/mol were synthesized via cross-linking of tetrafunctional star polymers. Both types of networks were then swollen in a monomer/cross-linker mixture, polymerized to form double networks, and characterized via uniaxial tensile testing. The onset of strain stiffening was found to occur later in regular networks than in random networks with the same modulus but was well-predicted by the target molecular weight between cross-links of each sample. These results indicate that the low- and high-strain behavior of polymer networks result from different molecular-scale features of the material and suggest that controlling network architecture offers new opportunities to both further fundamental understanding of architecture–property relationships and design materials with independently controlled moduli and strain stiffening responses. 

The effect of composition and morphology on mechanochemical activation in nanostructured block copolymers was investigated in a series of poly(methyl methacrylate)-block-poly(n-butyl acrylate)-block-poly(methyl methacrylate) (PMMA-b-PnBA-b-PMMA) triblock copolymers containing a force-responsive spiropyran unit in the center of the rubbery PnBA midblock. Triblock copolymers with identical PnBA midblocks and varying lengths of PMMA end-blocks were synthesized from a spiropyran-containing macroinitiatior via atom transfer radical polymerization, yielding polymers with volume fractions of PMMA ranging from 0.21 to 0.50. Characterization by transmission electron microscopy revealed that the polymers self-assembled into spherical and cylindrical nanostructures. Simultaneous tensile tests and optical measurements revealed that mechanochemical activation is strongly correlated to the chemical composition and morphologies of the triblock copolymers. As the glassy (PMMA) block content is increased, the overall activation increases, and the onset of activation occurs at lower strain but higher stress, which agrees with predictions from our previous computational work. These results suggest that the self-assembly of nanostructured morphologies can play an important role in controlling mechanochemical activation in polymeric materials and provide insights into how polymer composition and morphology impact molecular-scale force distributions.