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The ternary chalcogenide Cu3VSe4 (CVSe) with sulvanite structure has been theoretically predicted to be a promising candidate for photovoltaic applications due to its suitable band-gap for solar absorption and the relatively earth-abundant elements in its composition. To realize the absorber layer via an inexpensive route, printed thin-films could be fabricated from dispersions of nano-sized Cu3VSe4 precursors. Herein, cubic Cu3VSe4 nanocrystals were successfully synthesized via a hot-injection method. Similar with reported Cu3VS4 nanocrystals, Cu3VSe4 nanocrystals with cubic structure exhibit three absorption bands in the UV-Visible range indicative of a potential intermediate bandgap existence. A thin film fabricated by depositing the nanoparticlesmore »
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An, F. P. ; Bai, J. Z. ; Balantekin, A. B. ; Band, H. R. ; Beavis, D. ; Beriguete, W. ; Bishai, M. ; Blyth, S. ; Boddy, K. ; Brown, R. L. ; et al ( , Physical Review Letters)