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Learning a dynamical system requires stabilizing the unknown dynamics to avoid state blow-ups. However, the standard reinforcement learning (RL) methods lack formal stabilization guarantees, which limits their applicability for the control of real-world dynamical systems. We propose a novel policy optimization method that adopts Krasovskii's family of Lyapunov functions as a stability constraint. We show that solving this stability-constrained optimization problem using a primal-dual approach recovers a stabilizing policy for the underlying system even under modeling error. Combining this method with model learning, we propose a model-based RL framework with formal stability guarantees, Krasovskii-Constrained Reinforcement Learning (KCRL). We theoretically study KCRL with kernel-based feature representation in model learning and provide a sample complexity guarantee to learn a stabilizing controller for the underlying system. Further, we empirically demonstrate the effectiveness of KCRL in learning stabilizing policies in online voltage control of a distributed power system. We show that KCRL stabilizes the system under various real-world solar and electricity demand profiles, whereas standard RL methods often fail to stabilize.