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  2. Abstract

    Knowledge of the chemical speciation of particulate manganese (pMn) is important for understanding the biogeochemical cycling of Mn and other particle‐reactive elements. Here, we present the synchrotron‐based X‐ray spectroscopy‐derived average oxidation state (AOS) of pMn in the surface Arctic Ocean collected during the United States GEOTRACES Arctic cruise (GN01) in 2015. We show that the pMn AOS is <2.4 when sampled during the day and more than ∼3.0 when sampled at night. We hypothesize that an active light‐dependent redox cycle between dissolved Mn and particulate Mn(III/IV) exists during the day‐night cycle in the surface Arctic Ocean, which occurs on the timescale of hours. The magnitude of observed pMn AOS is likely determined by the net effect of the length of the previous night and integrated light level before the end of pMn sampling.

     
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  3. Abstract

    Although iron availability has been shown to limit ocean productivity and influence marine carbon cycling, the rates of processes driving iron's removal and retention in the upper ocean are poorly constrained. Using234Th‐ and sediment‐trap data, most of which were collected through international GEOTRACES efforts, we perform an unprecedented observation‐based assessment of iron export from and residence time in the upper ocean. The majority of these new residence time estimates for total iron in the surface ocean (0–250 m) fall between 10 and 100 days. The upper ocean residence time of dissolved iron, on the other hand, varies and cycles on sub‐annual to annual timescales. Collectively, these residence times are shorter than previously thought, and the rates and timescales presented here will contribute to ongoing efforts to integrate iron into global biogeochemical models predicting climate and carbon dioxide sequestration in the ocean in the 21st century and beyond.

     
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