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The vibrational branching ratios of SrOH for radiative decay to the ground electronic state, X2Σ+, from the first two electronically excited states, A2Π and B2Σ+, are determined experimentally at the ∼10−5 level. The observed small branching ratios enable the design of a full, practical laser-cooling scheme, including magneto-optical trapping and sub-Doppler laser cooling, with >104 photon scatters per molecule. Ab initio calculations sensitive to weak vibronic transitions are performed to facilitate the experimental measurement and analysis, and show good agreement with experiment.more » « less
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