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RR Lyrae stars play a central role in tracing phase-space structures within the Milky Way because they are easy to identify, are relatively luminous, and are found in large numbers in the Galactic bulge, disc, and halo. In this work, we present a new set of spectroscopic metallicity calibrations that use the equivalent widths of the Ca ii K and Balmer H γ and H δ lines to calculate metallicity values from low-resolution spectra. This builds on an earlier calibration from Layden by extending the range of equivalent widths which map between Ca ii K and the Balmer lines. We have developed the software rrlfe to apply this calibration to spectra in a consistent, reproducible, and extensible manner. This software is open-source and available to the community. The calibration can be updated with additional data sets in the future.

Carbon-enhanced metal-poor (CEMP) stars comprise almost a third of stars with [Fe/H] < −2, although their origins are still poorly understood. It is highly likely that one sub-class (CEMP-s stars) is tied to mass-transfer events in binary stars, while another sub-class (CEMP-no stars) are enriched by the nucleosynthetic yields of the first generations of stars. Previous studies of CEMP stars have primarily concentrated on the Galactic halo, but more recently they have also been detected in the thick disc and bulge components of the Milky Way. Gaia DR3 has provided an unprecedented sample of over 200 million low-resolution (R ≈ 50) spectra from the BP and RP photometers. Training on the CEMP catalogue from the SDSS/SEGUE database, we use XGBoost to identify the largest all-sky sample of CEMP candidate stars to date. In total, we find 58 872 CEMP star candidates, with an estimated contamination rate of 12 per cent. When comparing to literature high-resolution catalogues, we positively identify 60–68 per cent of the CEMP stars in the data, validating our results and indicating a high completeness rate. Our final catalogue of CEMP candidates spans from the inner to outer Milky Way, with distances as close as r ∼ 0.8 kpc from the Galactic centre, and as far as r > 30 kpc. Future higher resolution spectroscopic follow-up of these candidates will provide validations of their classification and enable investigations of the frequency of CEMP-s and CEMP-no stars throughout the Galaxy, to further constrain the nature of their progenitors.