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Suture zones located across the Tibetan region clearly demarcate the rift-and-drift and continental accretion history of the region. However, the intraplate responses to these marginal plate-tectonic events are rarely quantified. Our understanding of the Paleo-Tethyan orogenic system, which involved ocean opening and closing events to grow the central Asian continent, depends on the tectonic architecture and histories of major late Paleozoic−early Mesozoic orogenic belts. These opening and collision events were associated with coupled intracontinental deformation, which has been difficult to resolve due to subsequent overprinting deformation. The late Paleozoic−early Mesozoic Zongwulong Shan−Qinghai Nanshan belt in northern Tibet separates the Qilian and North Qaidam regions and is composed of Carboniferous−Triassic sedimentary materials and mantle-derived magmatic rocks. The tectonic setting and evolutional history of this belt provide important insight into the paleogeographic and tectonic relationships of the Paleo-Tethyan orogenic system located ∼200 km to the south. In this study, we integrated new and previous geological observations, detailed structural mapping, and zircon U-Pb geochronology data from the Zongwulong Shan−Qinghai Nanshan to document a complete tectonic inversion cycle from intraplate rifting to intracontinental shortening associated with the opening and closing of the Paleo-Tethyan Ocean. Carboniferous−Permian strata in the Zongwulong Shan were deposited in an intracontinental rift basin and sourced from both the north and the south. At the end of the Early−Middle Triassic, foreland molasse strata were deposited in the southern part of the Zongwulong Shan during tectonic inversion in the western part of the tectonic belt following the onset of regional contraction deformation. The Zongwulong Shan−Qinghai Nanshan system has experienced polyphase deformation since the late Paleozoic, including: (1) early Carboniferous intracontinental extension and (2) Early−Middle Triassic tectonic inversion involving reactivation of older normal faults as thrusts and folding of pre- and synrift strata. We interpret that the Zongwulong Shan−Qinghai Nanshan initiated as a Carboniferous−Early Triassic intracontinental rift basin related to the opening of the Paleo-Tethyan Ocean to the south, and it was then inverted during the Early−Middle Triassic closing of the Paleo-Tethyan Ocean. This work emphasizes that pre-Cenozoic intraplate structures related to the opening and closing of ocean basins in the Tethyan realm may be underappreciated across Tibet.more » « lessFree, publicly-accessible full text available May 24, 2025
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To overcome the difficulties of time-varying disturbance, model mismatch, and frequent operation in the rudder/fin joint control system, an interference model predictive control (I-MPC) rudder/fin joint control system with sliding mode observer is proposed. Considering that the model mismatch problem occurs when the ship is sailing, the model mismatch and external disturbance are regarded as the total disturbance. A discrete 3-degree-of-freedom ship disturbance mathematical model is established. The rudder angle and fin angle are selected as the system inputs, then a sliding mode observer is designed to observe the time-varying disturbance and system output in real time. Different from traditional MPC and feedforward compensation, I-MPC will predict the output based on the disturbance observation value, and the control law is solved under rudder/fin angle and angular velocity constraints. Simulation results show that the proposed method improves the tracking performance and anti-disturbance performance of the rudder/fin system. The observer has high observation accuracy for constant, sinusoidal, and time-varying disturbances. Mechanism wear and energy loss caused by frequent operation are avoided.
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Abstract Low‐cost multivalent battery chemistries (Mg2+, Al3+) have been extensively investigated for large‐scale energy storage applications. However, their commercialization is plagued by the poor power density and cycle life of cathodes. A universal polyimides@CNT (PI@CNT) cathode is now presented that can reversibly store various cations with different valences (Li+, Mg2+, Al3+) at an extremely fast rate. The ion‐coordination charge storage mechanism of PI@CNT is systemically investigated. Full cells using PI@CNT cathodes and corresponding metal anodes exhibit long cycle life (>10000 cycles), fast kinetics (>20 C), and wide operating temperature range (−40 to 50 °C), making the low‐cost industrial polyimides universal cathodes for different multivalent metal batteries. The stable ion‐coordinated mechanism opens a new foundation for the development of high‐energy and high‐power multivalent batteries.
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Abstract Low‐cost multivalent battery chemistries (Mg2+, Al3+) have been extensively investigated for large‐scale energy storage applications. However, their commercialization is plagued by the poor power density and cycle life of cathodes. A universal polyimides@CNT (PI@CNT) cathode is now presented that can reversibly store various cations with different valences (Li+, Mg2+, Al3+) at an extremely fast rate. The ion‐coordination charge storage mechanism of PI@CNT is systemically investigated. Full cells using PI@CNT cathodes and corresponding metal anodes exhibit long cycle life (>10000 cycles), fast kinetics (>20 C), and wide operating temperature range (−40 to 50 °C), making the low‐cost industrial polyimides universal cathodes for different multivalent metal batteries. The stable ion‐coordinated mechanism opens a new foundation for the development of high‐energy and high‐power multivalent batteries.