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Goethite is a major iron-bearing sedimentary mineral on Earth. In this study, we conducted in situ high-pressure x-ray diffraction, Raman, and electrical impedance spectroscopy measurements of goethite using a diamond anvil cell (DAC) at room temperature and high pressures up to 32 GPa. We observed feature changes in both the Raman spectra and electrical resistance at about 5 and 11 GPa. However, the x-ray diffraction patterns show no structural phase transition in the entire pressure range of the study. The derived pressure-volume (P-V) data show a smooth compression curve with no clear evidence of any second-order phase transition. Fitting the volumetric data to the second-order Birch–Murnaghan equation of state yields V0 = 138.9 ± 0.5 Å3 and K0 = 126 ± 5 GPa.more » « less
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Friedman, Elliot S. ; Bittinger, Kyle ; Esipova, Tatiana V. ; Hou, Likai ; Chau, Lillian ; Jiang, Jack ; Mesaros, Clementina ; Lund, Peder J. ; Liang, Xue ; FitzGerald, Garret A. ; et al ( , Proceedings of the National Academy of Sciences)
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Schubert, Susanne ; Wong, Jared ; Feng, Jun ; Karkare, Siddharth ; Padmore, Howard ; Ruiz-Osés, Miguel ; Smedley, John ; Muller, Erik ; Ding, Zihao ; Gaowei, Mengjia ; et al ( , Journal of Applied Physics)