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Abstract Many possible interior compositions exist for sub-Neptunes: ice-poor, ice-rich, and water-dominated interiors can all match the measured masses and radii. Motivated by a recent theory of carbon-rich planet formation outside the refractory organic carbon “soot line” and observations of carbon-rich protoplanetary disks around late M dwarfs, we propose another possible sub-Neptune composition: a carbon-rich composition consisting of an iron-silicate core, a carbon layer, and a hydrogen/helium-dominated envelope. We show that the interiors of three prototypical sub-Neptunes with high-quality spectral observations—TOI-270 d, GJ 1214 b, and K2-18 b—are consistent with carbon-rich compositions if they have ≤100 times solar metallicity atmospheres. We further show that carbon-rich interiors lead to atmospheric compositions that match Hubble Space Telescope and JWST observations. Simulated carbon-rich TOI-270 d transmission spectra pass theχ²test under a wide range of C/O, haze, and cloud scenarios. K2-18 b spectral models are broadly consistent with observations but require additional sources for carbon species to be fully compatible. GJ 1214 b models, however, are incompatible with observations, ruling out a carbon-rich interior composition, if the atmosphere of the planet is primordial and reflects the interior C/O. 

Abstract We report the validation of multiple planets transiting the nearby (d= 12.8 pc) K5V dwarf HD 101581 (GJ 435, TOI–6276, TIC 397362481). This system consists of at least two Earth-size planets whose orbits are near a mutual 4:3 mean-motion resonance, HD 101581 b ( $R_p={0.956}_{-0.061}^{+0.063}{R}_{\oplus }$ ,P= 4.47 days) and HD 101581c ( $R_p={0.990}_{-0.070}^{+0.070}{R}_{\oplus }$ ,P= 6.21 days). Both planets were discovered in Sectors 63 and 64 TESS observations and statistically validated with supporting ground-based follow-up. We also identify a signal that probably originates from a third transiting planet, TOI-6276.03 ( $R_p={0.982}_{-0.098}^{+0.114}{R}_{\oplus }$ ,P= 7.87 days). These planets are remarkably uniform in size and their orbits are evenly spaced, representing a prime example of the “peas-in-a-pod” architecture seen in other compact multiplanet systems. AtV= 7.77, HD 101581 is the brightest star known to host multiple transiting planets smaller than 1.5R_⊕. HD 101581 is a promising system for atmospheric characterization and comparative planetology of small planets.