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Creators/Authors contains: "Lovi, Jacob"

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  1. ; ; ; (, The Journal of Physical Chemistry C)
    Free, publicly-accessible full text available April 10, 2026
  2. ; (, Journal of Non-Crystalline Solids)
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  3. ; (, The Journal of Chemical Physics)
    The effects of atomic mass in terms of its zero-point vibrational energy, on molar volume, glass transition temperature Tg, and viscosity are studied in glassy and supercooled B2O3 liquids using boron isotope substitutions. The molar volume decreases and Tg and isothermal viscosity increase on the substitution of lighter 10B isotopes with the heavier 11B isotopes. These effects are argued to be a manifestation of the higher zero-point vibrational energy of the lighter isotope, which along with the anharmonicity of the potential well, results in a longer equilibrium inter-atomic distance and larger mean-square displacement with respect to that for the heavier isotope. The isotope effect on viscosity is increasingly enhanced as the temperature approaches Tg, which is shown to be consistent with the prediction of the elastic models of viscous flow and shear relaxation. 
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  4. ; ; ; ; (, Acta Materialia)
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