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Solid-state batteries are attractive energy storage systems as a result of their inherent safety, but their development hinges on advanced solid-state electrolytes (SSEs). Most SSEs remain largely confined to single-anion systems (e.g., sulfides, oxides, halides, and polymers). Through mixed-anion design strategy, we develop crystalline Li₃Ta₃O₄Cl₁₀(LTOC) and its derivatives with excellent ionic conductivities (up to 13.7 millisiemens per centimeter at 25°C) and electrochemical stability. The LTOC structure features mixed-anion spiral chains, consisting of corner-shared oxygen and terminal chlorine atoms, which induces continuous “tetrahedron-tetrahedron” Li-ion migration pathways with low energy barriers. Additionally, LTOC demonstrates holistic cathode compatibility, enabling solid-state batteries operation at 4.9 volts versus Li/Li⁺and low temperature, down to −50°C. These findings describe a promising class of superionic conductors for high-performance solid-state batteries. 

Abstract Motivated by the high-performance solid-state lithium batteries enabled by lithium superionic conductors, sodium superionic conductor materials have great potential to empower sodium batteries with high energy, low cost, and sustainability. A critical challenge lies in designing and discovering sodium superionic conductors with high ionic conductivities to enable the development of solid-state sodium batteries. Here, by studying the structures and diffusion mechanisms of Li-ion versus Na-ion conducting solids, we reveal the structural feature of face-sharing high-coordination sites for fast sodium-ion conductors. By applying this feature as a design principle, we discover a number of Na-ion conductors in oxides, sulfides, and halides. Notably, we discover a chloride-based family of Na-ion conductors Na_xM_yCl₆(M = La–Sm) with UCl₃-type structure and experimentally validate with the highest reported ionic conductivity. Our findings not only pave the way for the future development of sodium-ion conductors for sodium batteries, but also consolidate design principles of fast ion-conducting materials for a variety of energy applications. 

Abstract Accurate pulsar astrometric estimates are essential to almost all high-precision pulsar timing experiments. Traditional pulsar timing techniques refine these estimates by including them as free parameters when fitting a model to observed pulse time-of-arrival measurements. However, reliable submilliarcsecond astrometric estimations require years of observations. Even then, power from red noise can be inadvertently absorbed into astrometric parameter fits. This effect biases the resulting estimates and reduces the sensitivity to red noise processes, including gravitational waves (GWs). In this work, we seek to mitigate these shortcomings by using pulsar astrometric estimates derived from very long baseline interferometry (VLBI) as priors for the timing fit. First, we used VLBI and timing astrometric estimates of 18 millisecond pulsars to calibrate a rotation between the reference frames used in timing and VLBI, with a precision of ∼0.7 mas. Through this frame tie, we combined timing- and VLBI-based probabilities to obtain a maximum-posterior astrometric solution. We found offsets between our results and the timing-based astrometric solutions, which, if real, would lead to the absorption of spectral power at the frequencies of interest for single-source GW searches. However, we do not find significant power absorption due to astrometric fitting at the low-frequency domain of the GW background. 

Abstract Free-floating objects (FFOs) in interstellar space—rogue planets, brown dwarfs, and large asteroids that are not gravitationally bound to any star—are expected to be ubiquitous throughout the Milky Way. Recent microlensing surveys have discovered several free-floating planets that are not bound to any known stellar systems. Additionally, three interstellar objects, namely 1I/’Oumuamua, 2I/Borisov, and 3I/ATLAS, have been detected passing through our solar system on hyperbolic trajectories. In this work, we search for FFOs on hyperbolic orbits that pass near millisecond pulsars (MSPs), where their gravitational influence can induce detectable perturbations in pulse arrival times. Using the NANOGrav 15 yr narrow band dataset, which contains high-precision timing data for 68 MSPs, we conduct a search for such hyperbolic scattering events between FFOs and pulsars. Although no statistically significant events were detected, this nondetection enables us to place upper limits (ULs) on the number density of FFOs as a function of their mass within our local region of the Galaxy. For example, the UL on the number density for Jupiter-mass FFOs (∼10^−2.5–10^−3.5M_⊙) obtained from different pulsars ranges from 5.25 × 10⁶pc⁻³to 5.37 × 10⁹pc⁻³, while the UL calculated by combining results from all the pulsars is 6.03 × 10⁵pc⁻³. These results represent the first constraints on FFO population derived from pulsar timing data. 

Abstract PINTis a pure-Python framework for high-precision pulsar timing developed on top of widely used and well-tested Python libraries, supporting both interactive and programmatic data analysis workflows. We present a new frequentist framework withinPINTto characterize the single-pulsar noise processes present in pulsar timing data sets. This framework enables parameter estimation for both uncorrelated and correlated noise processes, as well as model comparison between different timing and noise models in a computationally inexpensive way. We demonstrate the efficacy of the new framework by applying it to simulated data sets as well as a real data set of PSR B1855+09. We also describe the new features implemented inPINTsince it was first described in the literature. 

Abstract The development of solid‐state sodium‐ion batteries (SSSBs) heavily hinges on the development of an superionic Na⁺conductor (SSC) that features high conductivity, (electro)chemical stability, and deformability. The construction of heterogeneous structures offers a promising approach to comprehensively enhancing these properties in a way that differs from traditional structural optimization. Here, this work exploits the structural variance between high‐ and low‐coordination halide frameworks to develop a new class of halide heterogeneous structure electrolytes (HSEs). The halide HSEs incorporating a UCl₃‐type high‐coordination framework and amorphous low‐coordination phase achieves the highest Na⁺conductivity (2.7 mS cm⁻¹at room temperature, RT) among halide SSCs so far. By discerning the individual contribution of the crystalline bulk, amorphous region, and interface, this work unravels the synergistic ion conduction within halide HSEs and provides a comprehensive explanation of the amorphization effect. More importantly, the excellent deformability, high‐voltage stability, and expandability of HSEs enable effective SSSB integration. Using a cold‐pressed cathode electrode composite of uncoated Na_0.85Mn_0.5Ni_0.4Fe_0.1O₂and HSEs, the SSSBs present stable cycle performance with a capacity retention of 91.0% after 100 cycles at 0.2 C.