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Attractive London dispersion effects were found to be responsible forca.half of the dissociation energy of the thiolate ligands in the first examples of M(EAr^iPr6)₃complexes of any metal with any donor [Ar^iPr6= C₆H₃-2,6-(C₆H₂-2,4,6-ⁱPr₃)₂]. 

Product of experts (PoE) are layered networks in which the value at each node is an AND (or product) of the values (possibly negated) at its inputs. These were introduced as a neural network architecture that can efficiently learn to generate high-dimensional data which satisfy many low-dimensional constraints---thereby allowing each individual expert to perform a simple task. PoEs have found a variety of applications in learning. We study the problem of identifiability of a product of experts model having a layer of binary latent variables, and a layer of binary observables that are iid conditional on the latents. The previous best upper bound on the number of observables needed to identify the model was exponential in the number of parameters. We show: (a) When the latents are uniformly distributed, the model is identifiable with a number of observables equal to the number of parameters (and hence best possible). (b) In the more general case of arbitrarily distributed latents, the model is identifiable for a number of observables that is still linear in the number of parameters (and within a factor of two of best-possible). The proofs rely on root interlacing phenomena for some special three-term recurrences. 

The terphenylthiolate ligands that stabilize the U(ii) complex U(SAr^iPr6)₂with U-arene interactions move out of the way in forming the U(vi) bis(imido) species U(SAr^iPr6)₂(NPh)₂(THF)₂or encapsulate a K⁺ion in the reduced complex KU(μ-SAr^iPr6)₂.