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Creators/Authors contains: "Martin, Caleb D."

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  1. ; ; ; (, Chemical Science)
    Carborane fused boron doped polycyclic aromatic hydrocarbons were accessed by dehydrobrominative and dehydrogenative borylation. 
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    Free, publicly-accessible full text available May 22, 2025
  2. ; ; ; ; (, Inorganic Chemistry)
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  3. ; (, Crystal Growth & Design)
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  4. ; ; (, Inorganic Chemistry)
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  5. ; ; ; ; (, Synlett)
    The additions of the phosphinoboronate ester Ph2PBpin to an antiaromatic borole and a borafluorene is reported. The Lewis acid/base adducts are obtained in excellent yields and represent the first P-donor adducts of Ph2PBpin. 
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  6. ; ; ; (, Dalton Transactions)
    Reactions of tris(ortho-carboranyl)borane with Lewis bases reveals only small bases bind. The tremendous bulk and Lewis acidity is leveraged in frustrated Lewis pair Si–H cleavage with a wider range of Lewis bases and greater efficacy than B(C6F5)3. 
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  7. ; ; ; ; (, Inorganic Chemistry)
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  8. ; ; ; (, Dalton Transactions)
    A series of anionic group 6 tricarbonyl and neutral rhodium dicarbonyl complexes featuring a boratabenzene (L1, with a phenyl on boron, a trimethylsilyl group on the adjacent carbon and methyl groups on the other carbons) and a borataphenanthrene ligand (L2, with a phenyl group on boron and a trimethylsilyl group on the adjacent carbon) are prepared. The donor ability of the boracyclic ligands is evaluated experimentally and theoretically by the stretching frequencies of the CO ancillary ligands. Overall, the donor ability of the ligands falls into the following trend: L1 > cyclopentadienyl > L2 > mesitylene. 
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  9. ; ; ; ; ; (, Dalton Transactions)
    The reaction of Ph 3 PAuN 3 with 9-Ph-9-borafluorene resulted in complexation of the azide to boron while a gold acetylide reacted with 9-Ph-9-borafluorene to insert the acetylide carbon to access a six-membered boracycle with an exocyclic double bond. 
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  10. ; (, Organometallics)
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