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BSTRACT:Piezoelectricmaterialsare used to fabricateacoustictransducersforbubblechambersin searchfor particlesof dark matter.It has been shownthat bubblesinitiatedby nuclearrecoilsemit acousticradiationdistinguishablefrom the phasetransitionscausedby alpha-decay�themain backgroundnoisein such searches.However,these piezoelectricmaterialsmust exhibitultralowradioactivityto minimizethe neutronbackgroundfor dark matterdetectionwhilepossessinghigh acousticsensitivity.Here,for the first time, we demonstrateradiopurehigh-performancepiezoelectricceramicsmeetingthe criteriafor acousticsensing.The screeningofradiopureprecursorsis performedto identifythose with low238U,232Th, and210Pbcontents.Usingthe radiopureprecursors,piezoelectricceramicswith varyingcompositionsare synthesized,and their electromechanicalacousticsensingperformanceis evaluated.Multiplesynthesismodificationssuch as dopingand texturingare utilizedtotailor the piezoelectriccoefficientsof the piezoelectricceramics,and the relationshipbetweenthe piezoelectriccoefficientsand acousticsensingperformanceof the ceramicsis investigated.Acoustictransducersfabricatedusing texturedPb(Mg1/3Nb2/3)O3−PbTiO3(PMN−PT)ceramicsare found to exhibitsuperioracousticsensitivitydue totheir high piezoelectrictransductioncoefficient(d33×g33). This study demonstratesa usefulfigure of merit (FOM)for acousticsensingin bubblechambersmore » « less