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Niu, Shanyuan ; Zhao, Boyang ; Ye, Kevin ; Bianco, Elisabeth ; Zhou, Jieyang ; McConney, Michael E. ; Settens, Charles ; Haiges, Ralf ; Jaramillo, Rafael ; Ravichandran, Jayakanth ( , Journal of Materials Research)Perovskite chalcogenides are gaining substantial interest as an emerging class of semiconductors for optoelectronic applications. High-quality samples are of vital importance to examine their inherent physical properties. We report the successful crystal growth of the model system, BaZrS 3 and its Ruddlesden–Popper phase Ba 3 Zr 2 S 7 by a flux method. X-ray diffraction analyses showed the space group of Pnma with lattice constants of a = 7.056(3) Å, b = 9.962(4) Å, and c = 6.996(3) Å for BaZrS 3 and P 4 2 / mnm with a = 7.071(2) Å, b = 7.071(2) Å, and c = 25.418(5) Å for Ba 3 Zr 2 S 7 . Rocking curves with full width at half maximum of 0.011° for BaZrS 3 and 0.027° for Ba 3 Zr 2 S 7 were observed. Pole figure analysis, scanning transmission electron microscopy images, and electron diffraction patterns also establish the high quality of the grown crystals. The octahedral tilting in the corner-sharing octahedral network is analyzed by extracting the torsion angles.
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Emori, Satoru ; Matyushov, Alexei ; Jeon, Hyung-Min ; Babroski, Christopher J. ; Nan, Tianxiang ; Belkessam, Amine M. ; Jones, John G. ; McConney, Michael E. ; Brown, Gail J. ; Howe, Brandon M. ; et al ( , Applied Physics Letters)
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Coexistence of Low Damping and Strong Magnetoelastic Coupling in Epitaxial Spinel Ferrite Thin FilmsEmori, Satoru ; Gray, Benjamin A. ; Jeon, Hyung-Min ; Peoples, Joseph ; Schmitt, Maxwell ; Mahalingam, Krishnamurthy ; Hill, Madelyn ; McConney, Michael E. ; Gray, Matthew T. ; Alaan, Urusa S. ; et al ( , Advanced Materials)
