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The El Niño Southern Oscillation (ENSO) is a climate variation that occurs in the Eastern Equatorial Pacific (EEP) ocean, which influences the position of the thermocline today. The ENSO cycle is split into three states: a normal state, an El Niño state, and a La Niña state. Each one is marked by different sea surface temperatures (SST). Under normal conditions, the trade winds push warm water westward, away from the coast of South America. This allows cool water to upwell the east and creates a zonal SST gradient. Every few years, the trade winds slow, preventing the flow of warm water. This increases the SST in the EEP and produces an El Niño. The winds can also strengthen and move more warm water westward. The heightened zonal SST gradient forms a La Niña. This project investigates past conditions in the EEP by reconstructing the mean position of the thermocline: a layer in the ocean where temperature rapidly changes with depth. In the modern ocean, the thermocline is shallower in the east, where SSTs are cool, and deeper in the west, where SSTs are warm. The more uniform SST gradient during an El Niño event flattens the zonal slope thermocline; the stronger gradient during a La Niña steepens it. The temperature proxy used to determine past thermocline positions is the isotopic composition of oxygen in foraminifera (δ18O). Foraminiferal δ18O increases with depth in the water column, as temperature decreases and density increases. Two species with contrasting depth-habitats were analyzed; Globigerinoides ruber, which lives near the surface above the thermocline, and Neogloboquadrina dutertrei, which lives in the lower thermocline. When the thermocline shifts, it changes their difference in δ18O. A smaller difference indicates a deeper thermocline and an El Niño-like state; a greater difference indicates a shallower thermocline and a La Niña-like state. The forams were collected from two deep-sea sediment cores. The first was Ocean Drilling Program (ODP) Leg 202 Site 1239 (0.67˚S, 82.08˚W, 1414 m) drilled in the east near the coast of Ecuador. The second was ODP Leg 138 Site 849 (0.10˚S, 110.31˚W, 3858 m) toward the west. Rather than identifying specific ENSO events, this method provides insight into the position of the thermocline and therefore the mean state of the EEP during the Holocene and last glacial period. 

In the marine sediment record, concentrations and isotope ratios of chromium (Cr) can be used to reconstruct ocean biogeochemical conditions. These reconstructions rely on a detailed understanding of the chemical pathways that Cr undergoes as it is transferred from the water column to the sediment record. We examined Cr concentrations in marine pore fluids and sediments from six continental margin sites, which can be grouped into two basic environments: (1) sites where sediments are oxygenated and rich in solid phase Mn (herein termed oxic), and (2) sites where sediments are organic C (Corg)-rich and oxygen is depleted (anoxic). We found Cr concentrations to be lower (maximum of 12 nM in pore fluids and 124 ppm sediment solid phase) at oxic sites compared with anoxic sites (maximum of 77 nM and 184 ppm). Our findings confirm previously published interpretations of dissolved Cr in pore fluids (Brumsack and Gieskes, 1983; Shaw et al., 1990). In oxic surface sediments, particulate Cr(III) can be oxidised by Mn oxides, which leads to elevated concentrations of dissolved Cr co-occurring at the same depth as elevated Mn concentrations in the sediment. Under these oxidising conditions, down-core sediments contain relatively low solid-phase Cr concentrations. In oxic sediments, Cr speciation reveals that most of the pore fluid Cr is in the Cr(VI) state. At the site where Mn oxide-rich sediments rest below an oxic water column, oxidative loss of Cr from the sediment to the bottom water leads to the lowest estimated Cr burial efficiency of the sites examined here. Under anoxic Corg-rich conditions, both pore fluids and sediment solid phases contain high Cr concentrations, with 40–80% of dissolved pore fluid Cr present as Cr(III). This enrichment of Cr appears to be tightly linked to the presence of high total organic carbon (TOC) content and scavenging of Cr by (organic) particles in the water column. Combined, these data highlight the strong dependence of Cr on both sedimentary redox conditions as well as biological productivity. Based on the data from modern continental margin sediments, we propose that Cr concentrations and isotope compositions of the authigenic sediment fraction may record a combination of redox conditions and biological productivity in the water column. If confirmed by Cr isotope analyses, these findings will add support for the notion that Cr may serve as a proxy for ocean biological and chemical sedimentological conditions. Thus, careful assessment of the impact of organic matter on Cr is required for reconstructions of redox conditions with sedimentary records. 

Understanding how the Intertropical Convergence Zone (ITCZ) responds to abrupt climate change is essential for reconstructing large‐scale atmospheric circulation across climate transitions. However, key differences between dynamical models and observational constraints on ITCZ movement remain unresolved. Here, we examine the Pb and Nd radiogenic isotope signatures of dust deposited in the central equatorial Pacific (CEP) from 160 to 105 kyr. We quantified the relative contributions of Northern Hemisphere‐ and Southern Hemisphere‐sourced dust to the CEP. In contrast with previous model estimates, we demonstrate that South America is an important source of dust to the CEP during glacial periods. Our new observations provide a critical data set for verifying dynamical arguments about tropical hydroclimate. We infer that the southernmost position of the ITCZ precipitation centroid occurs between 136 and 131 kyr, coincident with the timing of North Atlantic Heinrich Stadial Event 11 (136 to 129 kyr).