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Creators/Authors contains: "Miller, Alexander J."

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  1. ; ; ; ; ; ; ; ; ; (, Journal of the American Chemical Society)
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  2. ; ; ; ; (, Dalton Transactions)
    Proton-switchable access to seven-coordinate ONNO dicarboxamide and NNNN dicarboxamidate rhenium oxo complexes provides a platform for understanding thermodynamics and bonding in pentagonal bipyramidal complexes. 
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  3. ; (, Accounts of Chemical Research)
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  4. ; ; (, ACS Chemical Health & Safety)
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  5. ; ; ; (, Faraday Discussions)
    Porphyrin complexes are well-known in O 2 and CO 2 reduction, but their application to N 2 reduction is less developed. Here, we show that oxo and nitrido complexes of molybdenum supported by tetramesitylporphyrin (TMP) are effective precatalysts for catalytic N 2 reduction to ammonia, verified by 15 N 2 labeling studies and other control experiments. Spectroscopic and electrochemical studies illuminate some relevant thermodynamic parameters, including the N–H bond dissociation free energy of (TMP)MoNH (43 ± 2 kcal mol −1 ). We place these results in the context of other work on homogeneous N 2 reduction catalysis. 
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  6. ; ; ; ; ; ; ; ; ; (, Nature Reviews Methods Primers)
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  7. ; ; ; (, Inorganic Chemistry)
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  8. ; ; ; ; ; (, Organometallics)
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  9. ; ; ; ; ; ; ; ; ; ; et al (, ACS Catalysis)
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  10. ; ; ; (, Inorganic Chemistry)
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