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Abstract The broad-line region (BLR) size–luminosity relation has paramount importance for estimating the mass of black holes in active galactic nuclei (AGNs). Traditionally, the size of the H β BLR is often estimated from the optical continuum luminosity at 5100 Å, while the size of the H α BLR and its correlation with the luminosity is much less constrained. As a part of the Seoul National University AGN Monitoring Project, which provides 6 yr photometric and spectroscopic monitoring data, we present our measurements of the H α lags of high-luminosity AGNs. Combined with the measurements for 42 AGNs from the literature, we derive the size–luminosity relations of the H α BLR against the broad H α and 5100 Å continuum luminosities. We find the slope of the relations to be 0.61 ± 0.04 and 0.59 ± 0.04, respectively, which are consistent with the H β size–luminosity relation. Moreover, we find a linear relation between the 5100 Å continuum luminosity and the broad H α luminosity across 7 orders of magnitude. Using these results, we propose a new virial mass estimator based on the H α broad emission line, finding that the previous mass estimates based on scaling relations in the literature are overestimated by up to 0.7 dex at masses lower than 10 7 M ⊙ .