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Pan, Hao ; Colville, Marshall J. ; Supekar, Nitin T. ; Azadi, Parastoo ; Paszek, Matthew J. ( , ACS Synthetic Biology)
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Pan, Hao ; Li, Fei ; Liu, Yao ; Zhang, Qinghua ; Wang, Meng ; Lan, Shun ; Zheng, Yunpeng ; Ma, Jing ; Gu, Lin ; Shen, Yang ; et al ( , Science)Dielectric capacitors with ultrahigh power densities are fundamental energy storage components in electrical and electronic systems. However, a long-standing challenge is improving their energy densities. We report dielectrics with ultrahigh energy densities designed with polymorphic nanodomains. Guided by phase-field simulations, we conceived and synthesized lead-free BiFeO 3 -BaTiO 3 -SrTiO 3 solid-solution films to realize the coexistence of rhombohedral and tetragonal nanodomains embedded in a cubic matrix. We obtained minimized hysteresis while maintaining high polarization and achieved a high energy density of 112 joules per cubic centimeter with a high energy efficiency of ~80%. This approach should be generalizable for designing high-performance dielectrics and other functional materials that benefit from nanoscale domain structure manipulation.
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Shurer, Carolyn R. ; Kuo, Joe Chin-Hun ; Roberts, LaDeidra Monét ; Gandhi, Jay G. ; Colville, Marshall J. ; Enoki, Thais A. ; Pan, Hao ; Su, Jin ; Noble, Jade M. ; Hollander, Michael J. ; et al ( , Cell)