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This qualitative study examines how race/ethnicity and gender influence the transformation of student-faculty relationships into valued forms of social capital for students career-related opportunities career opportunities within Science, Technology, Mathematics, and Engineering (STEM) contexts. Through retrospective interviews with 40 STEM graduates, the data revealed: (1) that experiences of racism and sexism among women of color affected their ability to attend office hours and build strong relationships with professors; (2) that while White females experienced sexism from faculty, their White privilege lessened the negative effects associated with their gender; (3) that being exposed to diverse faculty facilitated conversations between female students and students of color and their professors about their career pathways; and (4) that the negative influence of race/ethnicity and gender on student-faculty relationships was alleviated, but not eliminated, through research engagement.