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  1. Free, publicly-accessible full text available March 1, 2025
  2. Abstract

    The cycling of marine particulate matter is critical for sequestering carbon in the deep ocean and in marine sediments. Biogenic minerals such as calcium carbonate (CaCO3) and opal add density to more buoyant organic material, facilitating particle sinking and export. Here, we compile and analyze a global data set of particulate organic carbon (POC), particulate inorganic carbon (PIC, or CaCO3), and biogenic silica (bSi, or opal) concentrations collected using large volume pumps (LVPs). We analyze the distribution of all three biogenic phases in the small (1–53 μm) and large (>53 μm) size classes. Over the entire water column 76% of POC exists in the small size fraction. Similarly, the small size class contains 82% of PIC, indicating the importance of small‐sized coccolithophores to the PIC budget of the ocean. In contrast, 50% of bSi exists in the large size fraction, reflecting the larger size of diatoms and radiolarians compared with coccolithophores. We use PIC:POC and bSi:POC ratios in the upper ocean to document a consistent signal of shallow mineral dissolution, likely linked to biologically mediated processes. Sediment trap PIC:POC and bSi:POC are elevated with respect to LVP samples and increase strongly with depth, indicating the concentration of mineral phases and/or a deficit of POC in large sinking particles. We suggest that future sampling campaigns pair LVPs with sediment traps to capture the full particulate field, especially the large aggregates that contribute to mineral‐rich deep ocean fluxes, and may be missed by LVPs.

     
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  3. Abstract

    Quantifying variability in, and identifying the mechanisms behind, East Asian dust production and transport across the last several million years is essential for constraining future dust emissions and deposition. Our current understanding of East Asian dust dynamics through the Quaternary is primarily limited to low‐resolution records from the North Pacific Ocean, those from the Chinese Loess Plateau (CLP), and paleoenvironmental reconstructions from arid basins. All are susceptible to sediment winnowing and focusing as well as input of poorly constrained or unidentified non‐dust detrital material. To avoid these limitations, we examine high‐resolution, constant flux proxy‐derived dust fluxes from the North Pacific and find evidence for higher glacial dust fluxes in the late Pliocene‐early Pleistocene compared to the late Pleistocene‐Holocene. Our results suggest decreasing dust transported to the mid‐latitude North Pacific Ocean from eastern Asia across the Quaternary. This observation is ostensibly at odds with previous dust records from marine sediments and the CLP, and with the perception of higher East Asian dust production and transport during the late Pleistocene associated with the amplification of glaciations. We provide three possible scenarios to describe the ∼2,700‐ky evolution of eastern Asia glacial dust dynamics, and discuss them in the context of sediment production, availability, and atmospheric circulation. Our data and proposed driving mechanisms not only raise questions about the framework typically used to interpret dust archives from East Asia and the North Pacific Ocean, but also provide a roadmap for hypothesis testing and future work necessary to produce better‐constrained records of paleo‐dust fluxes.

     
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  5. Abstract

    The deep ocean has long been recognized as the reservoir that stores the carbon dioxide (CO2) removed from the atmosphere during Pleistocene glacial periods. The removal of glacial atmospheric CO2into the ocean is likely modulated by an increase in the degree of utilization of macronutrients at the sea surface and enhanced storage of respired CO2in the deep ocean, known as enhanced efficiency of the biological pump. Enhanced biological pump efficiency during glacial periods is most easily documented in the deep ocean using proxies for oxygen concentrations, which are directly linked to respiratory CO2levels. We document the enhanced storage of respired CO2during the Last Glacial Maximum (LGM) in the Pacific Southern Ocean and deepest Equatorial Pacific using records of deglacial authigenic manganese, which form as relict peaks during increases in bottom water oxygen (BWO) concentration. These peaks are found at depths and regions where other oxygenation histories have been ambiguous, due to diagenetic alteration of authigenic uranium, another proxy for BWO. Our results require that the entirety of the abyssal Pacific below approximately 1,000 m was enriched in respired CO2and depleted in oxygen during the LGM. The presence of authigenic Mn enrichment in the deep Equatorial Pacific for each of the last five deglaciations suggests that the storage of respired CO2in the deep ocean is a ubiquitous feature of late‐Pleistocene ice ages.

     
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  6. Abstract

    One of the primary sources of micronutrients to the sea surface in remote ocean regions is the deposition of atmospheric dust. Geographic patterns in biogeochemical processes such as primary production and nitrogen fixation that require micronutrients like iron (Fe) are modulated in part by the spatial distribution of dust supply. Global models of dust deposition rates are poorly calibrated in the open ocean, owing to the difficulty of determining dust fluxes in sparsely sampled regions. We present new estimates of dust and Fe input rates from measurements of dissolved and particulate thorium isotopes230Th and232Th on theFS SonneSO245 section (GEOTRACES process study GPpr09) in the South Pacific. We first discuss high‐resolution upper water column profiles of Th isotopes and the implications for the systematics of dust flux reconstructions from seawater Th measurements. We find dust fluxes in the center of the highly oligotrophic South Pacific Gyre that are the lowest of any mean annual dust input rates measured in the global oceans, but that are 1–2 orders of magnitude higher than those estimated by global dust models. We also determine dust‐borne Fe fluxes and reassess the importance of individual Fe sources to the surface South Pacific Gyre, finding that dust dissolution, not vertical or lateral diffusion, is the primary Fe source. Finally, we combine our estimates of Fe flux in dust with previously published cellular and enzymatic quotas to determine theoretical upper limits on annual average nitrogen fixation rates for a given Fe deposition rate.

     
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  7. Abstract

    The Southern Ocean hosts complex connections between ocean physics, chemistry, and biology. Changes in these connections are hypothesized to be responsible for significant alterations of ocean biogeochemistry and carbon storage both on glacial‐interglacial timescales and in the future due to anthropogenic forcing. Isotopes of thorium (230Th and232Th) and protactinium (231Pa) have been widely applied as tools to study paleoceanographic conditions in the Southern Ocean. However, understanding of the chemical behavior of these isotopes in the modern Southern Ocean has been limited by a paucity of high‐resolution observations. In this study, we present measurements of dissolved230Th,231Pa, and232Th on a meridional transect along 170°W from 67°S to 54°S in the Pacific sector of the Southern Ocean, with high vertical and meridional sampling resolution. We find Th/Pa fractionation factors below 1, highlighting the preferential removal of Pa relative to Th in a region with low lithogenic inputs where the particle flux is dominated by biogenic opal. We also find steep gradients in all three of these isotopes along neutral density surfaces from north to south, demonstrating the importance of isopycnal mixing in transporting these nuclides to the Southern Ocean. Our results suggest that231Pa and230Th in the Southern Ocean are highly sensitive tracers of physical transport that may find use in studies of Southern Ocean biogeochemical‐physical connections in the past, present, and future.

     
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  8. Abstract

    Processes controlling dissolved barium (dBa) were investigated along the GEOTRACES GA03 North Atlantic and GP16 Eastern Tropical Pacific transects, which traversed similar physical and biogeochemical provinces. Dissolved Ba concentrations are lowest in surface waters (∼35–50 nmol kg−1) and increase to 70–80 and 140–150 nmol kg−1in deep waters of the Atlantic and Pacific transects, respectively. Using water mass mixing models, we estimate conservative mixing that accounts for most of dBa variability in both transects. To examine nonconservative processes, particulate excess Ba (pBaxs) formation and dissolution rates were tracked by normalizing particulate excess230Th activities. Th‐normalized pBaxsfluxes, with barite as the likely phase, have subsurface maxima in the top 1,000 m (∼100–200 μmol m−2 year−1average) in both basins. Barite precipitation depletes dBa within oxygen minimum zones from concentrations predicted by water mass mixing, whereas inputs from continental margins, particle dissolution in the water column, and benthic diffusive flux raise dBa above predications. Average pBaxsburial efficiencies along GA03 and GP16 are ∼37% and 17%–100%, respectively, and do not seem to be predicated on barite saturation indices in the overlying water column. Using published values, we reevaluate the global freshwater dBa river input as 6.6 ± 3.9 Gmol year−1. Estuarine mixing processes may add another 3–13 Gmol year−1. Dissolved Ba inputs from broad shallow continental margins, previously unaccounted for in global marine summaries, are substantial (∼17 Gmol year−1), exceeding terrestrial freshwater inputs. Revising river and shelf dBa inputs may help bring the marine Ba isotope budget more into balance.

     
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  9. Abstract

    Sinking particles strongly regulate the distribution of reactive chemical substances in the ocean, including particulate organic carbon and other elements (e.g., P, Cd, Mn, Cu, Co, Fe, Al, and232Th). Yet, the sinking fluxes of trace elements have not been well described in the global ocean. The U.S. GEOTRACES campaign in the North Atlantic (GA03) offers the first data set in which the sinking flux of carbon and trace elements can be derived using four different radionuclide pairs (238U:234Th;210Pb:210Po;228Ra:228Th; and234U:230Th) at stations co‐located with sediment trap fluxes for comparison. Particulate organic carbon, particulate P, and particulate Cd fluxes all decrease sharply with depth below the euphotic zone. Particulate Mn, Cu, and Co flux profiles display mixed behavior, some cases reflecting biotic remineralization, and other cases showing increased flux with depth. The latter may be related to either lateral input of lithogenic material or increased scavenging onto particles. Lastly, particulate Fe fluxes resemble fluxes of Al and232Th, which all have increasing flux with depth, indicating a dominance of lithogenic flux at depth by resuspended sediment transported laterally to the study site. In comparing flux estimates derived using different isotope pairs, differences result from different timescales of integration and particle size fractionation effects. The range in flux estimates produced by different methods provides a robust constraint on the true removal fluxes, taking into consideration the independent uncertainties associated with each method. These estimates will be valuable targets for biogeochemical modeling and may also offer insight into particle sinking processes.

     
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