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Hasan, Mohammad J. ; Petrie, Frankie A. ; Johnson, Ashley E. ; Peltan, Joshua ; Gannon, Meredith ; Busch, Robert T. ; Leontsev, Serhiy O. ; Vasquez, Erick S. ; Urena-Benavides, Esteban E. ( , Cellulose)null (Ed.)
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Bheemireddy, Sambasiva R. ; Hussain, Waseem A. ; Uddin, Ain ; Du, Yachu ; Hautzinger, Matthew P. ; Kevorkian, Paul V. ; Petrie, Frankie A. ; Plunkett, Kyle N. ( , Chemical Communications)Isomerically pure 5,11-dibromo-2,8-dihexylanthra[2,3- b :76- b ′]dithiophene, a brominated analog of anthracenedithiophene (ADT), was prepared and utilized for a palladium catalyzed cyclopentannulation reaction with 3,3′-dimethoxy-phenylacetylene to give cyclopentannulated ADT (CP-ADTs). A further Scholl cyclodehydrogenation reaction gave contorted aromatics with large splay angles, low optical gaps, and low LUMOs.more » « less