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Shape-morphing structures that can reconfigure their shape to adapt to diverse tasks are highly desirable for intelligent machines in many interdisciplinary fields. Shape memory polymers are one of the most widely used stimuli-responsive materials, especially in 3D/4D printing, for fabricating shape-morphing systems. They typically go through a hot-programming step to obtain the shape-morphing capability, which possesses limited freedom of reconfigurability. Cold-programming, which directly deforms the structure into a temporary shape without increasing the temperature, is simple and more versatile but has stringent requirements on material properties. Here, we introduce grayscale digital light processing (g-DLP) based 3D printing as a simple and effective platform for fabricating shape-morphing structures with cold-programming capabilities. With the multimaterial-like printing capability of g-DLP, we develop heterogeneous hinge modules that can be cold-programmed by simply stretching at room temperature. Different configurations can be encoded during 3D printing with the variable distribution and direction of the modular-designed hinges. The hinge module allows controllable independent morphing enabled by cold programming. By leveraging the multimaterial-like printing capability, multi-shape morphing structures are presented. The g-DLP printing with cold-programming morphing strategy demonstrates enormous potential in the design and fabrication of shape-morphing structures.

Printable feedstocks that can produce lightweight, robust, and ductile structures with tunable and switchable conductivity are of considerable interest for numerous application spaces. Combining the specific properties of commodity thermoplastics with the unique electrical and redox properties of conducting polymers (CPs) presents new opportunities for the field of printed (bio)electronics. Here, we report on the direct ink write (DIW) printing of ink formulations based on polyaniline-dinonylnaphthalene sulfonic acid (PANI-DNNSA), which has been synthesized in bulk quantities (∼400 g). DNNSA imparts solubility to PANI up to 50 mg mL −1 , which allows the use of various additives to tune the rheological behavior of the inks without significantly compromising the electrical properties of the printed structures, which reach conductivities in the range of <10 −7 –10 0 S cm −1 as a function of ink formulation and post treatment used. Fumed silica (FS) and ultra-high molecular weight polystyrene (UHMW-PS) additives are leveraged to endow printability and shape retention to inks, as well as to compare the use of traditional rheological modifiers with commodity thermoplastics on CP feedstocks for tailored DIW printing. We show that the incorporation of UHMW-PS into these ink formulations is critical for obtaining high crack resistance in printedmore »structures. This work serves as a guide for future ink designs of CPs with commodity thermoplastics and their subsequent DIW printing to yield conductive architectures and devices for various applications.« less

Multimaterial additive manufacturing has important applications in various emerging fields. However, it is very challenging due to material and printing technology limitations. Here, we present a resin design strategy that can be used for single-vat single-cure grayscale digital light processing (g-DLP) 3D printing where light intensity can locally control the conversion of monomers to form from a highly stretchable soft organogel to a stiff thermoset within in a single layer of printing. The high modulus contrast and high stretchability can be realized simultaneously in a monolithic structure at a high printing speed (z-direction height 1 mm/min). We further demonstrate that the capability can enable previously unachievable or hard-to-achieve 3D printed structures for biomimetic designs, inflatable soft robots and actuators, and soft stretchable electronics. This resin design strategy thus provides a material solution in multimaterial additive manufacture for a variety of emerging applications.

Shape-changing objects are prized for applications ranging from acoustics to robotics. We report sub-millimetre bubbles that reversibly and rapidly change not only their shape but also their topological class, from sphere to torus, when subjected to a simple pressure treatment. Stabilized by a solid-like film of nanoscopic protein “particles”, the bubbles may persist in toroidal form for several days, most of them with the relative dimensions expected of Clifford tori. The ability to cross topological classes reversibly and quickly is enabled by the expulsion of protein from the strained surfaces in the form of submicron assemblies. Compared to structural modifications of liquid-filled vesicles, for example by slow changes in solution osmolality, the rapid inducement of shape changes in bubbles by application of pressure may hasten experimental investigations of surface mechanics, even as it suggests new routes to lightweight materials with high surface areas.

This project aims to enhance students’ learning in foundational engineering courses through oral exams based on the research conducted at the University of California San Diego. The adaptive dialogic nature of oral exams provides instructors an opportunity to better understand students’ thought processes, thus holding promise for improving both assessments of conceptual mastery and students’ learning attitudes and strategies. However, the issues of oral exam reliability, validity, and scalability have not been fully addressed. As with any assessment format, careful design is needed to maximize the benefits of oral exams to student learning and minimize the potential concerns. Compared to traditional written exams, oral exams have a unique design space, which involves a large range of parameters, including the type of oral assessment questions, grading criteria, how oral exams are administered, how questions are communicated and presented to the students, how feedback were provided, and other logistical perspectives such as weight of oral exam in overall course grade, frequency of oral assessment, etc. In order to address the scalability for high enrollment classes, key elements of the project are the involvement of the entire instructional team (instructors and teaching assistants). Thus the project will create a new training program tomore »prepare faculty and teaching assistants to administer oral exams that include considerations of issues such as bias and students with disabilities. The purpose of this study is to create a framework to integrate oral exams in core undergraduate engineering courses, complementing existing assessment strategies by (1) creating a guideline to optimize the oral exam design parameters for the best students learning outcomes; and (2) Create a new training program to prepare faculty and teaching assistants to administer oral exams. The project will implement an iterative design strategy using an evidence-based approach of evaluation. The effectiveness of the oral exams will be evaluated by tracking student improvements on conceptual questions across consecutive oral exams in a single course, as well as across other courses. Since its start in January 2021, the project is well underway. In this poster, we will present a summary of the results from year 1: (1) exploration of the oral exam design parameters, and its impact in students’ engagement and perception of oral exams towards learning; (2) the effectiveness of the newly developed instructor and teaching assistants training programs (3) The development of the evaluation instruments to gauge the project success; (4) instructors and teaching assistants experience and perceptions.« less