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  1. Abstract

    There are lingering questions about the effectiveness of the watch, warning, and advisory system (WWA) used to convey weather threats in the United States. Recently there has been a shift toward alternative communication strategies such as the impact-based forecast. The study reported here compared users’ interpretation of a color-coded impact-based prototype designed for email briefings, to a legacy WWA format. Participants, including emergency managers and members of the public, saw a weather briefing and rated event likelihood, severity, damage, and population affected. Then they recommended emergency response actions. Each briefing described the severity of the weather event and the degree of impact on population and property. In one condition a color-coded impacts scale was added to the text description. In another, an advisory and/or warning was added to the text description. These were compared with the text-only control. Both emergency managers and members of the public provided higher ratings for event likelihood, severity, damage, and population affected and recommended a greater response for higher impact levels regardless of format. For both groups, the color-coded format decreased ratings for lower-impact events. Among members of the public, the color-coded format also led to increases for many ratings and greater response at higher levels relative to the other two conditions. However, the highest ratings among members of the public were in the WWA condition. Somewhat surprisingly, the only effect of the WWA format on emergency managers was toreduceaction recommendations, probably because of the inclusion of the “advisory” in some briefings.

     
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  2. Abstract. Gas–particle partitioning of water-soluble organic compounds plays a significant role in influencing the formation, transport, and lifetime oforganic aerosols in the atmosphere, but is poorly characterized. In this work, gas- and particle-phase concentrations of isoprene oxidation products(C5-alkene triols and 2-methylterols), levoglucosan, and sugar polyols were measured simultaneously at a suburban site of the western Yangtze RiverDelta in east China. All target polyols were primarily distributed into the particle phase (85.9 %–99.8 %). Given the uncertainties inmeasurements and vapor pressure predictions, a dependence of particle-phase fractions on vapor pressures cannot be determined. To explore the impactof aerosol liquid water on gas–particle partitioning of polyol tracers, three partitioning schemes (Cases 1–3) were proposed based onequilibriums of gas vs. organic and aqueous phases in aerosols. If particulate organic matter (OM) is presumed as the only absorbing phase(Case 1), the measurement-based absorptive partitioning coefficients (Kp,OMm) of isoprene oxidation products and levoglucosan were more than 10 times greater than predicted values (Kp,OMt). The agreement betweenKp,OMm and Kp,OMt was substantially improved when solubility in a separate aqueous phase wasincluded, whenever water-soluble and water-insoluble OM partitioned into separate (Case 2) or single (Case 3) liquid phases,suggesting that the partitioning of polyol tracers into the aqueous phase in aerosols should not be ignored. The measurement-based effective Henry'slaw coefficients (KH,em) of polyol tracers were orders of magnitude higher than their predicted values in pure water(KH,wt). Due to the moderate correlations between log⁡(KH,em/KH,wt) andmolality of sulfate ions, the gap between KH,em and KH,wt of polyol tracers could not be fullyparameterized by the equation defining “salting-in” effects and might be ascribed to mechanisms of reactive uptake, aqueous phase reaction,“like-dissolves-like” principle, etc. These study results also partly reveal the discrepancy between observation and modeling of organicaerosols. 
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