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Abstract U-Pb geochronology by isotope dilution–thermal ionization mass spectrometry (ID-TIMS) has the potential to be the most precise and accurate of the deep time chronometers, especially when applied to high-U minerals such as zircon. Continued analytical improvements have made this technique capable of regularly achieving better than 0.1% precision and accuracy of dates from commonly occurring high-U minerals across a wide range of geological ages and settings. To help maximize the long-term utility of published results, we present and discuss some recommendations for reporting ID-TIMS U-Pb geochronological data and associated metadata in accordance with accepted principles of data management. Further, given that the accuracy of reported ages typically depends on the interpretation applied to a set of individual dates, we discuss strategies for data interpretation. We anticipate that this paper will serve as an instructive guide for geologists who are publishing ID-TIMS U-Pb data, for laboratories generating the data, the wider geoscience community who use such data, and also editors of journals who wish to be informed about community standards. Combined, our recommendations should increase the utility, veracity, versatility, and “half-life” of ID-TIMS U-Pb geochronological data. 

Dynamic models of the protoplanetary disk indicate there should be large-scale material transport in and out of the inner Solar System, but direct evidence for such transport is scarce. Here we show that the ε 50 Ti-ε 54 Cr-Δ 17 O systematics of large individual chondrules, which typically formed 2 to 3 My after the formation of the first solids in the Solar System, indicate certain meteorites (CV and CK chondrites) that formed in the outer Solar System accreted an assortment of both inner and outer Solar System materials, as well as material previously unidentified through the analysis of bulk meteorites. Mixing with primordial refractory components reveals a “missing reservoir” that bridges the gap between inner and outer Solar System materials. We also observe chondrules with positive ε 50 Ti and ε 54 Cr plot with a constant offset below the primitive chondrule mineral line (PCM), indicating that they are on the slope ∼1.0 in the oxygen three-isotope diagram. In contrast, chondrules with negative ε 50 Ti and ε 54 Cr increasingly deviate above from PCM line with increasing δ 18 O, suggesting that they are on a mixing trend with an ordinary chondrite-like isotope reservoir. Furthermore, the Δ 17 O-Mg# systematics of these chondrules indicate they formed in environments characterized by distinct abundances of dust and H 2 O ice. We posit that large-scale outward transport of nominally inner Solar System materials most likely occurred along the midplane associated with a viscously evolving disk and that CV and CK chondrules formed in local regions of enhanced gas pressure and dust density created by the formation of Jupiter. 

The demise of the Late Paleozoic Ice Age has been hypothesized as diachronous, occurring first in western South America and progressing eastward across Africa and culminating in Australia over an ~60 m.y. period, suggesting tectonic forcing mechanisms that operate on time scales of 106 yr or longer. We test this diachronous deglaciation hypothesis for southwestern and south-central Gondwana with new single crystal U-Pb zircon chemical abrasion thermal ionizing mass spectrometry (CA-TIMS) ages from volcaniclastic deposits in the Paraná (Brazil) and Karoo (South Africa) Basins that span the terminal deglaciation through the early postglacial period. Intrabasinal stratigraphic correlations permitted by the new high-resolution radioisotope ages indicate that deglaciation across the south to southeast Paraná Basin was synchronous, with glaciation constrained to the Carboniferous. Cross-basin correlation reveals two additional glacial-deglacial cycles in the Karoo Basin after the terminal deglaciation in the Paraná Basin. South African glaciations were penecontemporaneous (within U-Pb age uncertainties) with third-order sequence boundaries (i.e., inferred base-level falls) in the Paraná Basin. Synchroneity between early Permian glacial-deglacial events in southwestern to south-central Gondwana and pCO2 fluctuations suggest a primary CO2 control on ice thresholds. The occurrence of renewed glaciation in the Karoo Basin, after terminal deglaciation in the Paraná Basin, reflects the secondary influences of regional paleogeography, topography, and moisture sources.