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Abstract Two-dimensional (2D) semiconductors are promising candidates for optoelectronic application and quantum information processes due to their inherent out-of-plane 2D confinement. In addition, they offer the possibility of achieving low-dimensional in-plane exciton confinement, similar to zero-dimensional quantum dots, with intriguing optical and electronic properties via strain or composition engineering. However, realizing such laterally confined 2D monolayers and systematically controlling size-dependent optical properties remain significant challenges. Here, we report the observation of lateral confinement of excitons in epitaxially grown in-plane MoSe2quantum dots (~15-60 nm wide) inside a continuous matrix of WSe2monolayer film via a sequential epitaxial growth process. Various optical spectroscopy techniques reveal the size-dependent exciton confinement in the MoSe2monolayer quantum dots with exciton blue shift (12-40 meV) at a low temperature as compared to continuous monolayer MoSe2. Finally, single-photon emission (g2(0) ~ 0.4) was also observed from the smallest dots at 1.6 K. Our study opens the door to compositionally engineered, tunable, in-plane quantum light sources in 2D semiconductors.more » « lessFree, publicly-accessible full text available December 1, 2025
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Kim, Gwangwoo; Kim, Hyong Min; Kumar, Pawan; Rahaman, Mahfujur; Stevens, Christopher E.; Jeon, Jonghyuk; Jo, Kiyoung; Kim, Kwan-Ho; Trainor, Nicholas; Zhu, Haoyue; et al (, ACS Nano)
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