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Aerosol Jet Printing shows a lot of promise for the future of printable electronics. It is compatible with a wide range of materials and can be printed on nearly any type of surface features because of its 3–5 mm standoff distance from the substrate. However, nearly all materials printed require some form of post-sintering processing to reduce the electrical resistance. Many companies develop these materials, but only provide a narrow range of post processing results to demonstrate the achievable conductivity values. In this paper, a design of experiment (DOE) is presented that demonstrates a way to characterize any material for Aerosol Jet Printing during and after post sintering processing by measuring conductivity with different time and temperature values. From these results, a linear regression model can be made to develop an equation that predicts conductivity at a given time-temperature value. This paper applies this method to Clariant Ag ink and sinters silver pads in an oven. A linear regression model is successfully developed that fits the data very well. From this model, an equation is derived to predict the conductivity of the Clariant Ag ink for any time-temperature value. Although only demonstrated with an oven and one type of ink, this method of experimentation and model development can be done with any material and any post processing method. 

Aerosol Jet Printing is a novel micron-scale printing technology capable of handling a variety of materials due to a large print material viscosity range and high substrate standoff distance of 3-5 mm. To finalize the properties of printed materials, a form of post-processing is often required. A current widely applicable post-processing technique exists in traditional oven curing. However, oven curing greatly restricts the viable substrates as well as curing time. Intense Pulsed Light (IPL) offers the chance to greatly expand this substrate variety and decrease curing time. However, limited models currently exist to relate the finished material properties to the unique settings of current IPL technology. In this paper, an experiment is developed through a General Full Factorial Design of Experiments (DOE) model to characterize conductivity of Ag ink using IPL as a post processing technique. This is conducted through Novacentrix Ag ink (JSA426) by 3x3 mm Van der Pauw sensor pads cured using IPL. Sample pads were generated in triplicate over a range of Energy Levels, Counts and Durations for IPL and the resulting conductivity measured. The collected conductivity data was then analyzed using ANOVA to determine the significant interactions. From this, a regression model is developed to predict the conductivity for any Energy-Count-Duration value. The methods employed are applicable to any post-processing technique, and further optimization of the model is proposed for future work. 

Bistable elements are candidate structures for the evolving field of MEMS-based no-power event-driven sensors. In this paper, we present a strategy for producing bistable elements and investigate two compatible bilayer material systems for their realization using MEMS technology. Both bilayer systems leverage thermally-grown silicon dioxide as the principal stress-producing layer and a second material (either polyimide or aluminum) as the main structural layer. Arrays of buckled circular diaphragms, ranging in diameter from 100μm to 700μm in 50μm increments, were fabricated and their performances were compared to modeled and FEA-simulated results. In all cases, the diaphragms buckled when DRIE-released as expected, and their buckled experimental heights were within 9.1% of the theory and 1.8% of the FEA prediction. Interestingly, the smaller diameter structures exhibited a directional bias which we investigate and forecast using FEA. These bistable mechanical elements have the ability to serve as building blocks for no-power threshold-driven smart switches. New contributions to the field include: (a) introduction of a new bistable material system made from aluminum and compressive oxide, (b) investigation of diaphragm diameter size as it related to the phenomena of bistability versus non-bistability, (c) FEA analysis of the critical transition between bistability and non-bistability, and (d) introduction of the ‘dome factor’ term to describe dome quality.

 

Rapid chemistry and processing development has increased the performance of perovskite solar cells (PSCs) in an unprecedented manner, yet postdeposition annealing impedes high‐throughput manufacturing. Herein, SnO₂and carbon charge transport films are fabricated entirely through an integrated robotic setup utilizing inkjet printing and intense pulse light (IPL) as a high‐speed postprocess annealing method; hence, process optimization is crucial for successful fabrication of PSCs. This work investigates the role of inkjet deposition parameters as well as IPL annealing on the morphology and uniformity of films with aid of spectroscopy and spectrophotometry. Initially PSCs exceeding 13% efficiency are developed by only fabricating the SnO₂film through the robotic setup, but spin coating all other films followed by IPL annealing to demonstrate successful fabrication of SnO₂layer. Finally, SnO₂and carbon back contact films are entirely fabricated through the integrated robotic setup in a high humid ambient environment (>60%), resulting in PSCs exceeding 5% efficiency. Unlike successful direct annealing of SnO₂wet films, IPL annealing of wet carbon severely damaged the phase and morphology necessitating rapid solvent removal before IPL annealing. This work establishes pioneering steps towards utilizing IPL in an entirely automated fabrication line, allowing for scalable fabrication of PSCs through non‐roll‐to‐roll.