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Cluster-Spin-Glass Magnetic Behavior and Morphology in the Coordination Polymer Alloys Fe _y Co _1–y BTT

https://doi.org/10.1021/jacs.3c07527

Ritchhart, Andrew; Chen, Zhihengyu; Behera, Agnish; Jeon, Ie-Rang; Chapman, Karena W.; Vaikuntanathan, Suriyanarayanan; Anderson, John S. (November 2023, Journal of the American Chemical Society)

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Structure and Magnetic Properties of Pseudo-1D Chromium Thiolate Coordination Polymers

https://doi.org/10.1021/acs.inorgchem.2c03991

Ritchhart, Andrew; Filatov, Alexander S.; Jeon, Ie-Rang; Anderson, John S. (February 2023, Inorganic Chemistry)

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Broad Electronic Modulation of Two-Dimensional Metal–Organic Frameworks over Four Distinct Redox States

https://doi.org/10.1021/jacs.3c00495

Wang, Lei; Sarkar, Arup; Grocke, Garrett L.; Laorenza, Daniel William; Cheng, Baorui; Ritchhart, Andrew; Filatov, Alexander S.; Patel, Shrayesh N.; Gagliardi, Laura; Anderson, John S. (April 2023, Journal of the American Chemical Society)

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Quantifying Ligand Exchange on InP Using an Atomically Precise Cluster Platform

https://doi.org/10.1021/acs.inorgchem.8b03524

Ritchhart, Andrew; Cossairt, Brandi M. (February 2019, Inorganic Chemistry)

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Conversion Reactions of Atomically Precise Semiconductor Clusters

https://doi.org/10.1021/acs.accounts.8b00365

Friedfeld, Max R.; Stein, Jennifer L.; Ritchhart, Andrew; Cossairt, Brandi M. (October 2018, Accounts of Chemical Research)

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Templated Growth of InP Nanocrystals with a Polytwistane Structure

https://doi.org/10.1002/anie.201711539

Ritchhart, Andrew; Cossairt, Brandi M. (January 2018, Angewandte Chemie International Edition)

Abstract We have synthesized InP nanocrystals of an unprecedented crystal phase at low temperature (35–100 °C) by templated growth of InP magic‐sized clusters. With the addition of stoichiometric equivalents of P(SiMe₃)₃to the starting cluster, we demonstrate nanocrystal growth mediated through a partial dissolution and recrystallization pathway. This growth process was monitored using a combination of in situ UV/Vis and³¹P NMR spectroscopy, revealing the intermediacy of smaller cluster species of higher symmetry. The nanocrystals that result from this templated growth exhibit a crystal structure that is neither zincblende nor wurtzite, and instead is derived from the original cluster. This structure is best described as a 3D polytwistane phase as deduced from a combination of X‐ray diffraction, Raman, and solid‐state NMR spectroscopy methods.
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